Rhodium(II) heptafluorobutyrate dimer

Name: Rhodium(II) heptafluorobutyrate dimer
SKU: ACM73755289-3
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Catalog NumberACM73755289-3

CAS Number73755-28-9

CategoryElectrolytes

Synonyms

DIRHODIUM(II) TETRAKIS(PERFLUOROBUTYRATE)

IUPAC Name

2,2,3,3,4,4,4-heptafluorobutanoic acid;rhodium;

Molecular Weight

1057.93

Molecular Formula

C₁₆F₂₈O₈Rh₂

Canonical SMILES

C(=O)(C(C(C(F)(F)F)(F)F)(F)F)O.C(=O)(C(C(C(F)(F)F)(F)F)(F)F)O.C(=O)(C(C(C(F)(F)F)(F)F)(F)F)O.C(=O)(C(C(C(F)(F)F)(F)F)(F)F)O.[Rh].[Rh];

InChI

InChI=1S/4C4HF7O2.2Rh/c4*5-2(6,1(12)13)3(7,8)4(9,10)11;;/h4*(H,12,13);;;

InChI Key

BOXUZZKOIQVEQP-UHFFFAOYSA-N;

Melting Point

>300° C (lit.)

Application

Rhodium(II) heptafluorobutyrate dimer serves as a versatile catalyst utilized in the catalytic preparation of macrocycles and the efficient synthesis of chiral β-substituted (E)-crotylsilanes. Its applications extend to facilitating carbene reactions of diazo compounds, hydrosilylation of alkenes and alkynes, as well as silyl carbonylation of alkynes, showcasing its pivotal role in advancing diverse chemical transformations.

Storage

room temperature

Complexity

488

Covalently-Bonded Unit Count

Exact Mass

1061.757g/mol

Heavy Atom Count

Monoisotopic Mass

1061.757g/mol

Rotatable Bond Count

Topological Polar Surface Area