Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L)

Name: Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L)
SKU: ACM15489277-5
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Catalog NumberACM15489277-5

CAS Number15489-27-7

CategoryElectrolytes

Synonyms

DilithiumTetrachlorocopper(II)(ca.2.5%inTetrahydrofuran,ca.0.1mol/L); Lithium tetrachlorocuprate, 0.1M in THF; KS-000017QU; Dilithium tetrachlorocuprate, 0.1M solution in THF, AcroSeal(R); AKOS030228377;

IUPAC Name

dilithium;tetrachlorocopper(2-);

Molecular Weight

219.226g/mol

Molecular Formula

Cl4CuLi2;

Canonical SMILES

[Li+].[Li+].Cl[Cu-2](Cl)(Cl)Cl;

InChI

InChI=1S/4ClH.Cu.2Li/h4*1H;;;/q;;;;+2;2*+1/p-4;

InChI Key

HCJWWBBBSCXJMS-UHFFFAOYSA-J;

Application

Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L) is a versatile and organic soluble copper-based catalyst that serves multiple purposes in synthetic chemistry. Its primary function is to enhance the efficiency of coupling reactions between alkyl halides and alkyl Grignard reagents. Additionally, it is employed in the halogenation of pyrimidine nucleosides. As a catalyst, it is used in catalytic quantities to improve the displacement reactions of halides and allylic acetates when interacting with Grignard reagents. Furthermore, it plays a crucial stoichiometric role in opening epoxides and aziridines, expanding its applicability in various chemical transformations. This clear orange to brown-red solution exemplifies an essential tool for chemists seeking to optimize reaction pathways and achieve desired outcomes in organic synthesis.

Storage

Flammables area

Complexity

19.1

Covalently-Bonded Unit Count

Exact Mass

218.834g/mol

Heavy Atom Count

Monoisotopic Mass

216.837g/mol

Topological Polar Surface Area

0A^2