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Potassium osmate(vi)dihydrate

Catalog NumberACM10022669-2

CAS Number10022-66-9

CategoryElectrolytes

Potassium osmate(vi)dihydrate
Synonyms
POTASSIUM OSMIUM OXIDE(VI);POTASSIUM OSMATE DIHYDRATE;POTASSIUM OSMATE(VI) DIHYDRATE;Potassium osmium oxide(VI) dihydrate;Potassium osmate(VI) dihydrate, 51.0-52.0% Os;Potassiumosmate(VI)dihydrate,99%;Osmate (OsO42-), dipotassium, dihydrate, (T-4)-;potass
IUPAC Name
dipotassium;dioxido(dioxo)osmium;dihydrate
Molecular Weight
368.5g/mol
Molecular Formula
H4K2O6Os
Canonical SMILES
O.O.[O-][Os](=O)(=O)[O-].[K+].[K+]
InChI
InChI=1S/2K.2H₂O.4O.Os/h;;2*1H2;;;;;/q2*+1;;;;;2*-1;
InChI Key
DGODWNOPHMXOTR-UHFFFAOYSA-N
Purity
Os 51.5%
Appearance
amaranthine crystalline powder or red-green octahedral crystals
Application
Potassium osmate(VI) dihydrate is a violet crystalline powder primarily used as a catalyst in oxidative reactions. Its main purpose is to facilitate the cleavage of olefins into ketones and carboxylic acids. Additionally, it plays a crucial role in the intramolecular amidohydroxylation of carbamoyloxytethered olefins to produce hydroxy oxazolidinones. This compound is also a key reagent in the synthesis of amphidinolide B, a substance known for its significant antitumor properties against various human tumor cells. As an oxidant, potassium osmate(VI) dihydrate is characterized by its diamagnetic nature in the VI oxidation state and presents as a purple salt. It is water-soluble, though it gradually decomposes in aqueous solutions, and it remains insoluble in ethereal and alcoholic solvents.
Complexity
62.2
Covalently-Bonded Unit Count
5
Exact Mass
369.88968g/mol
Formal Charge
0
Hazard Statements
H301 + H311 + H331
Heavy Atom Count
9
MDL Number
MFCD00149919
Monoisotopic Mass
369.88968g/mol
Rotatable Bond Count
0
Safety Description
Danger
UNII
5M2BWQ2TYJ
UN Number
UN 3288 6.1 / PGII
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