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  • Bis(triphenylphosphine)nickel(II) dichloride

    • Bis(triphenylphosphine)nickel(II) dichloride

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    Catalog Number
    ACM14264165
    CAS Number
    14264-16-5
    Product Name
    Bis(triphenylphosphine)nickel(II) dichloride
    Structure
    Category
    Vapor Deposition Precursors; Polymerization Reagents
    Synonyms
    Dichlorobis(triphenylphosphine)nickel(II),
    NiCl2(PPh3)2,
    Nickel(II)bis(triphenylphosphine) dichloride
    Description
    dichloridobis(triphenylphosphane)nickel(II) is a metal phosphine complex with the formula NiCl2[P(C6H5)3]2. It is a dark blue crystalline solid. It is used as a catalyst for organic synthesis.
    IUPAC Name
    dichloronickel;triphenylphosphane
    Molecular Weight
    654.17
    Molecular Formula
    C36H32Cl2NiP2-
    Canonical SMILES
    Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
    InChI
    1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2,ZBRJXVVKPBZPAN-UHFFFAOYSA-L
    InChI Key
    ZBRJXVVKPBZPAN-UHFFFAOYSA-L
    Melting Point
    250ºC (dec.)
    Flash Point
    181.7ºC
    Appearance
    Dark gray solid
    Application
    Ni(PPh3)2Cl2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine.
    Storage
    room temp
    Assay
    99.99% trace metals basis
    Complexity
    204
    Covalently-Bonded Unit Count
    3
    EC Number
    238-154-8
    Exact Mass
    652.055322g/mol
    Form
    powder or crystals
    Formal Charge
    0
    Hazard Class
    6.1(b)
    Heavy Atom Count
    41
    Log P
    4.04770
    MDL Number
    MFCD00009592
    Monoisotopic Mass
    652.055322g/mol
    Packaging
    10 g in glass bottle
    Rotatable Bond Count
    6
    Storage Conditions
    Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
    WGK Germany
    3
    MSDS
    Download MSDS
    COA
    Download COA
    Spec Sheet
    Download Spec Sheet
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