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MeO-4PACz

  • Product Name: MeO-4PACz, (4-(3,6-Dimethoxy-9H-carbazol-9-yl)butyl)phosphonic acid
  • Catalog Number: ALCM2922526563
  • CAS Number: 2922526-56-3

Product Description

Chemical Structure of MeO-4PACz

MeO-4PACz (4-(3,6-Dimethoxy-9H-carbazol-9-yl)butyl)phosphonic acid) is a high-performance self-assembled monolayer (SAM) material developed for use as a hole transport or extraction layer in advanced perovskite and organic photovoltaic devices. It comprises a hydrophobic, electron-rich 3,6-dimethoxycarbazole core, a flexible butyl linker, and a phosphonic acid anchoring group, which ensures strong chemical bonding to metal oxide substrates such as ITO.

As a methoxy-substituted analog of Me-4PACz, this material offers enhanced surface wettability and improved deposition reproducibility—critical for achieving uniform perovskite layers and high device yields. These attributes make it particularly well-suited for inverted (p-i-n) perovskite solar cells and non-fullerene acceptor (NFA)-based polymer solar cells.

The extended alkyl spacer in MeO-4PACz allows for co-anchoring of smaller molecules such as (aminomethyl)phosphonic acid (AMP), which can infiltrate and fill nanoscale voids within the monolayer. This interfacial densification improves surface passivation, minimizes trap-assisted recombination, and ultimately enhances device stability and operational efficiency.

Thanks to its excellent solubility and solution-processability at low concentrations (typically 1 mM), MeO-4PACz provides a scalable, low-temperature alternative to PEDOT:PSS. Its compatibility with various wet-coating techniques enables reproducible interface engineering in both research and large-scale fabrication environments.

Product Information

Item Details
CAS Number 2922526-56-3
Catalog Number ALCM2922526563
Synonyms (4-(3,6-Dimethoxy-9H-carbazol-9-yl)butyl)phosphonic acid
Chemical Formula C18H22NO5P
Molecular Weight 363.34 g/mol
Purity > 98% (HPLC)
Appearance White powder
Melting Point 197 °C
HOMO / LUMO HOMO = 5.32 eV, LUMO = 2.05 eV
Absorption Not available
Fluorescence Not available

Application Highlights

  • Hole-selective contact layer in inverted (p-i-n) perovskite solar cells
  • Hole transport layer for organic photovoltaic devices
  • Interface engineering in tandem or multi-junction solar cells
  • PEDOT:PSS replacement with superior optoelectronic performance

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