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Vanadyl acetylacetonate

Catalog Number
ACM3153262-3
CAS Number
3153-26-2
Product Name
Vanadyl acetylacetonate
Structure
Category
Solution Deposition Precursors
Synonyms
Bis(acetylacetonato)oxovanadium
IUPAC Name
(Z)-4-Hydroxypent-3-en-2-one;oxovanadium
Molecular Weight
267.17
Molecular Formula
C10H16O5V
Canonical SMILES
CC(=CC(=O)C)O.CC(=CC(=O)C)O.O=[V]
InChI
InChI=1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/b2*4-3-;
InChI Key
FSJSYDFBTIVUFD-SUKNRPLKSA-N
Boiling Point
140 °C
Melting Point
235 °C
Flash Point
79 °C
Purity
95%+
Density
1.4 g/cm³
Solubility
Slightly soluble in water
Appearance
Blue or green powder
Application
Vanadyl acetylacetonate is utilized predominantly as a versatile catalyst with multiple applications in chemical processes. It serves as a precursor in the synthesis of vanadium dioxide thin films, which are essential for developing "intelligent" window coatings and enhancing data storage technologies. As a catalyst, it plays a crucial role in various chemical reactions, including hydroxyl-directed epoxidation of olefins, asymmetric oxidation of disulfides, the Mannich reaction, and the sulfoxidation of alkanes. Through these diverse applications, vanadyl acetylacetonate significantly contributes to advancements in coatings, data storage, and numerous catalytic processes in modern chemistry.
Storage
Store below +30 °C
Complexity
253
Covalently-Bonded Unit Count
3
Defined Atom Stereocenter Count
0
EC Number
221-590-8
Exact Mass
267.043731
Formal Charge
0
Heavy Atom Count
16
Hydrogen Bond Acceptor Count
5
Hydrogen Bond Donor Count
2
Isomeric SMILES
C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.O=[V]
MeSH Entry Terms
OBAAV;oxobis(acetylacetonato)vanadium IV
Monoisotopic Mass
267.043731
Rotatable Bond Count
2
Topological Polar Surface Area
91.7 Ų
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