Titania paste, reflector

Catalog Number

ACMA00000087

Product Name

Titania paste, reflector

Category

3D Printing Materials

Synonyms

TiO2 paste, Dyesol(R) WER2-O

Description

Titania paste, the reflector is a precursor for titania, that forms a mesoporous light scattering layer on the fluorine doped tin oxide (FTO) substrates. It is used in a variety of electrochemical devices to improve electron mobility and power efficiency.

IUPAC Name

dioxotitanium

Molecular Weight

79.87g/mol

Molecular Formula

TiO₂;TiO₂;TiO₂;O2Ti

Canonical SMILES

O=[Ti]=O

InChI

1S/2O.Ti

InChI Key

GWEVSGVZZGPLCZ-UHFFFAOYSA-N

Boiling Point

4532 to 5432 °F at 760 mm Hg (NTP, 1992)

Melting Point

3380 °F (decomposes) (NTP, 1992);1855 °C;1855 °C;3326-3362°F;3326-3362°F

Density

3.9 to 4.2 (NTP, 1992);4.23;3.9-4.3 g/cm³;4.26;4.26

Solubility

less than 1 mg/mL at 68° F (NTP, 1992);Insoluble in water and organic solvents. Dissolves slowly in hydrofluoric acid and in hot concentrated sulphuric acid.;Insoluble in water;Soluble in hot concentrated sulfuric acid; in hydrofluoric acid; insoluble in hydrochloric acid, nitric acid or diluted sulfuric acid;INSOL IN ORG SOLVENTS;SOLUBLE IN ALKALI;Solubility in water: none;Insoluble

Application

Light scattering titania paste can be coated on the primary transparent layer of TiO2 to form a bilayered titanium film. It can be used as a negative electrode for dye sensitized solar cells (DSSCs).Scattering Reflector Titania Paste can be used in conjunction with Transparent Titania Paste for enhanced DSSC performance in applications where transparency is not required.Scattering Titania Paste contains highly dispersed anatase scattering particles (150nm to 250nm). This paste produces a non-active scattering layer when applied onto a pre-printed active layer.After drying; this paste must be fired - together with the pre-printed active layers - at or above 500°C. This results in an opaque sintered layer; with a thickness of ~3μm for one printed layer; when using a 90T mesh screen.Storage: Store in the dark at 20°C

Storage

room temp

Color/Form

White, tetragonal crystals;White powder in two crystalline forms, anatase and rutile;AMORPHOUS, INFUSIBLE POWDER;White powder

Complexity

18.3

Covalently-Bonded Unit Count

1

EC Number

236-675-5;215-282-2;215-280-1;236-675-5;619-318-1

Exact Mass

79.93777g/mol

Form

paste (White)

Formal Charge

0

Heavy Atom Count

3

ICSC Number

0338

MDL Number

MFCD00011269

MeSH Entry Terms

anatase;anatase titanium dioxide;brookite;food additive E171;nano-anatase;nano-TiO₂;rutile;Titania;titanium dioxide;titanium oxide;titanium white

Monoisotopic Mass

79.93777g/mol

NSC Number

15204

Odor

Odorless

Other Experimental

GRAVIMETRIC FACTOR: 0.33279;ANATASE: INDEX OF REFRACTION (NA): 2.554; 2.493; SPECIFIC GRAVITY: 3.84; BROOKITE: INDEX OF REFRACTION (NA): 2.583; 2.586; 2.741; SPECIFIC GRAVITY: 4.17 RUTILE: SPECIFIC GRAVITY: 4.26; INDEX OF REFRACTION (NA): 2.616; 2.903;Reactivity depends on previous heat treatment; prolonged heating produces less soluble material; made soluble by fusion with potassium bisulfate or alkali hydroxides or carbonates to form alkali titanates; Index of refraction: 2.7 (Titania crystals);RUTILE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: P4/MNM(136); 2 G FORMULA WT/UNIT CELL; X-RAY CRYSTALLOGRAPHIC DATA: AO= 4.5937 + OR - 0.0005; CO= 2.9618 + OR - 0.0010;ANATASE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: I41/AMD(141); 4 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 3.785 + OR - 0.002; CO= 9.514 + OR - 0.006;BROOKITE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: ORTHORHOMBIC; SPACE GROUP: PCAB (61); 8 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 5.456 + OR - 0.002; BO= 9.182 + OR - 0.005; CO= 5.143 + OR - 0.003;When substantially pure, a massive single crystal (boule) of rutile has properties of precious gem with a very light straw color and with reflectance, refraction and brilliance measuring greater than those of a diamond. ... high opacity and tinting values are claimed for rutile-like pigments.;Titania is ... large ... crystals (translucent water-white or with yellowish cast) these crystals have refractive index ... higher than diamonds ... but lack hardness of diamonds.;Possesses perhaps the greatest hiding power of all inorg white pigments;Brown tetragonal crystals; MP: 1560 °C; density: 3.9 g/cu cm /Titanium(IV)oxide (Anatase)/;White, orthorhombic crystals; density: 4.17 g/cu cm /Titanium(IV)oxide (Brookite)/;White, tetrahedral crystals; MP: 1843 °C; BBP: approximately 3000 °C; density: 4.17 g/cu cm. Insoluble in water, dilute acid; soluble in concentrated acid /Titanium(IV)oxide (Rutile)/

Packaging

5 g/20 g

Refractive Index

INDEX OF REFRACTION: 2.616; 2.903

Rotatable Bond Count

0

Vapor Pressure

0 mm Hg at 68 °F Essentially (NTP, 1992);0 mmHg (approx);0 mmHg (approx)

MSDS

COA

Spec Sheet