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  • Rhodium(II) acetate dimer

  • Rhodium(II) acetate dimer

    Catalog Number
    ACM15956282-1
    CAS Number
    15956-28-2
    Product Name
    Rhodium(II) acetate dimer
    Structure
    Category
    Salt; Electrolytes; Solution Deposition Precursors
    Synonyms
    Tetrakis-(mu-acetato)dirhodium
    IUPAC Name
    rhodium(2+);tetraacetate;
    Molecular Weight
    441.99
    Molecular Formula
    C8H12O8Rh2
    Canonical SMILES
    CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Rh+2].[Rh+2]
    InChI
    InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;2*+2/p-4
    InChI Key
    SYBXSZMNKDOUCA-UHFFFAOYSA-J
    Melting Point
    205 °C
    Purity
    98%
    Appearance
    Fresh green crystal
    Application
    Catalyst for insertion into C-H and X-H bonds.

    Catalyst for Ylide generation.

    Doyle−Kirmse Reaction of Allylic Sulfides with Diazoalkane

    Claisen rearrangement.

    Epoxides from aldehydes.

    Synthesis of aziridines from allylic N-tosyloxycarbamates.

    Rh/NHC catalyzed direct intermolecular arylation of C-H bonds.

    Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines.

    Rh-catalyzed cyclopropenations of ynamides.

    Tandem asymmetric aza-Darzens/ring-opening reactions.
    Storage
    Store below +30°C.
    Complexity
    25.5
    Covalently-Bonded Unit Count
    6
    Defined Atom Stereocenter Count
    0
    EC Number
    240-084-8
    Exact Mass
    441.86421
    Heavy Atom Count
    18
    Hydrogen Bond Acceptor Count
    8
    Hydrogen Bond Donor Count
    0
    Monoisotopic Mass
    441.86421
    Rotatable Bond Count
    0
    Topological Polar Surface Area
    161 Ų
    UNII
    NK3058Z56X
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