Catalog Number
ACM15956282-1
Product Name
Rhodium(II) acetate dimer
Category
Salt; Electrolytes; Solution Deposition Precursors
Synonyms
Tetrakis-(mu-acetato)dirhodium
IUPAC Name
rhodium(2+);tetraacetate;
Molecular Formula
C8H12O8Rh2
Canonical SMILES
CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Rh+2].[Rh+2]
InChI
InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;2*+2/p-4
InChI Key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
Appearance
Fresh green crystal
Application
Catalyst for insertion into C-H and X-H bonds.
Catalyst for Ylide generation.
Doyle−Kirmse Reaction of Allylic Sulfides with Diazoalkane
Claisen rearrangement.
Epoxides from aldehydes.
Synthesis of aziridines from allylic N-tosyloxycarbamates.
Rh/NHC catalyzed direct intermolecular arylation of C-H bonds.
Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines.
Rh-catalyzed cyclopropenations of ynamides.
Tandem asymmetric aza-Darzens/ring-opening reactions.
Storage
Store below +30°C.
Covalently-Bonded Unit Count
6
Defined Atom Stereocenter Count
0
Hydrogen Bond Acceptor Count
8
Hydrogen Bond Donor Count
0
Monoisotopic Mass
441.86421
Topological Polar Surface Area
161 Ų