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Rhodium(II) acetate dimer

Catalog Number
ACM15956282-1
CAS Number
15956-28-2
Product Name
Rhodium(II) acetate dimer
Structure
Category
Salt; Electrolytes; Solution Deposition Precursors
Synonyms
Tetrakis-(mu-acetato)dirhodium
IUPAC Name
rhodium(2+);tetraacetate;
Molecular Weight
441.99
Molecular Formula
C8H12O8Rh2
Canonical SMILES
CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Rh+2].[Rh+2]
InChI
InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;2*+2/p-4
InChI Key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
Melting Point
205 °C
Purity
98%
Appearance
Fresh green crystal
Application
Catalyst for insertion into C-H and X-H bonds.

Catalyst for Ylide generation.

Doyle−Kirmse Reaction of Allylic Sulfides with Diazoalkane

Claisen rearrangement.

Epoxides from aldehydes.

Synthesis of aziridines from allylic N-tosyloxycarbamates.

Rh/NHC catalyzed direct intermolecular arylation of C-H bonds.

Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines.

Rh-catalyzed cyclopropenations of ynamides.

Tandem asymmetric aza-Darzens/ring-opening reactions.
Storage
Store below +30°C.
Complexity
25.5
Covalently-Bonded Unit Count
6
Defined Atom Stereocenter Count
0
EC Number
240-084-8
Exact Mass
441.86421
Heavy Atom Count
18
Hydrogen Bond Acceptor Count
8
Hydrogen Bond Donor Count
0
Monoisotopic Mass
441.86421
Rotatable Bond Count
0
Topological Polar Surface Area
161 Ų
UNII
NK3058Z56X
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