CAS 156074-98-5 Poly(3-hexylthiophene-2,5-diyl)

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Poly(3-hexylthiophene-2,5-diyl)

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Catalog Number

ACM156074985-3

Product Name

Poly(3-hexylthiophene-2,5-diyl)

Structure

CAS

156074-98-5

Category

3D Printing Materials

Synonyms

P3HT

Description

Poly(3-hexylthiophene-2,5-diyl) (P3HT) is a poly(alkylthiophene) based semiconducting polymer that is hydrophobic at neutral state and has π-π conjugation in its backbone. It has a hole mobility is in the range of 10-3-10-1 cm2V-1s-1 and is commonly used in the development of field-effect transistors (FETs) for a wide range of applications.
Poly(3-hexylthiophene) (P3HT) is a regioregular semiconducting polymer. It is used in organic electronics primarily because of its regular end-to-end arrangement of side chain, which allows efficient p- p stacking of the conjugated backbones. On account of the alkyl side group, P3HT is rendered hydrophobic in neutral state. Solution-to-solid phase transformation and thin film formation of poly(3-hexylthiophene) (P3HT) was reported in a study.

Molecular Weight

average Mw 50,000-100,000

Molecular Formula

(C10H14S)n

Melting Point

238 °C

Appearance

Solid

Application

Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
For the characterization and solid-state properties of this polymer, see J. Am. Chem. Soc. .
P3HT, an electron donor that acts as a semiconducting active layer in combination with an electron acceptor like fullerene derivative (6,6)-phenyl C61-butyric acid methylester (PCBM), can be used to fabricate bulk heterojunction (HJT) based organic solar cells (OSCs). Volatile organic compounds (VOCs)and electric sensor devices can be developed by using Langmuir-Schaefer (LS) films of P3HT and poly(3-octylthiophene)(P3OT). It can also be used with polystyrene to process a nano-scaled polymeric coating through spray coating onto carbon nanotube (CNT) powders.
Poly(3-hexylthiophene-2,5-diyl) may be used to fabricate ZnO nanowire arrays based photodiode. Regio- regular poly(3-hexylthiophene-2,5-diyl) may find extensive use as a semiconducting layer in organic thin film field effect transistor (FETs).

Storage

room temp

Complexity

141

Compound Is Canonicalized

Yes

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Defined Bond Stereocenter Count

Deprecated CAS

1202693-12-6

Exact Mass

325.91625g/mol

Feature

Fluorescence: λex 443 nm; λem 568 nm in chloroform

Form

ITO/NiO/P3HT/PC61BM/LiF/Al[9]• Short-circuit current density (Jsc): 11.3 mA/cm² • Open-circuit voltage (Voc): 0.64 V• Fill Factor (FF): 0.69• Power Conversion Efficiency (PCE): 5.16 %

Formal Charge

Heavy Atom Count

Hydrogen Bond Acceptor Count

Hydrogen Bond Donor Count

Isotope Atom Count

MDL Number

MFCD00217686

Monoisotopic Mass

323.91830g/mol

Packaging

1 g in glass bottle

Rotatable Bond Count