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Methacrylaldehyde

Catalog Number
ACMA00017371
Product Name
Methacrylaldehyde
Category
Polymers
Description
Methacrylaldehyde appears as a colorless liquid. Less dense than water. May be toxic by ingestion, inhalation and skin absorption. Severely irritating to skin and eyes. Used to make plastics.;Liquid;COLOURLESS LIQUID WITH PUNGENT ODOUR. TURNS PALE YELLOW ON EXPOSURE TO LIGHT AND AIR.;COLOURLESS-TO-YELLOW LIQUID WITH PUNGENT ODOUR.
IUPAC Name
2-methylprop-2-enal
Molecular Weight
70.09g/mol
Molecular Formula
C4H6O;CH3CH=CHCHO;C4H6O;CH2=C(CH3)CHO;C4H6O
Canonical SMILES
CC(=C)C=O
InChI
InChI=1S/C4H6O/c1-4(2)3-5/h3H,1H2,2H3
InChI Key
STNJBCKSHOAVAJ-UHFFFAOYSA-N
Boiling Point
68.4 °C;68.4 °C;104 °C;68 °C
Melting Point
-81.0 °C;-81 °C;-76.5 °C (trans), -69 °C (cis);-81 °C
Flash Point
35 °F (NFPA, 2010);35 °F (2 °C) (OPEN CUP);13 °C c.c.;-15 °C
Density
0.849 @ 25 °C/4 °C;Relative density (water = 1): 0.85;Relative density (water = 1): 0.8
Solubility
0.81 M;MISCIBLE WITH WATER, ETHANOL, ETHER;Water solubility = 5.9% (59,000 mg/L) at 20 °C;Solubility in water, g/100ml at 20 °C: 15-18 (freely soluble);Solubility in water, g/100ml at 20 °C: 6 (soluble)
Application
Methacrylaldehyde, a colourless to light yellow liquid, serves as a vital component in the production of various industrial materials such as polymers, synthetic resins, and plastics. It functions as a raw material in the synthesis of methylmalonic acid and thermoplastic fuels and plays a role in the preparation of 2,3-dibromo-2-methyl-propionaldehyde. Beyond its industrial applications, methacrylaldehyde is utilized in scientific studies, particularly those examining the effects of limonene and terpene oxidation products. Being an enal, methacrylaldehyde contributes significantly to both manufacturing processes and research endeavors.
Color/Form
COLORLESS LIQUID
Complexity
54.7
Covalently-Bonded Unit Count
1
EC Number
201-150-1
Exact Mass
70.041865g/mol
Formal Charge
0
Heat of Vaporization
29.0 kJ/mol @ 101.3 kPa
Heavy Atom Count
5
ICSC Number
0241;1259
Log P
0.63 (calculated)
MeSH Entry Terms
2-methylacrolein;methacrolein;methacrylaldehyde
Monoisotopic Mass
70.041865g/mol
NSC Number
8260
Other Experimental
CONVERSION FACTORS: 1 MG/L= 349 PPM; 1 PPM= 2.8 MG/CU M;Liquid molar volume = 0.08320 cu m/kmol;Heat of Formation (gas) = -70.8 kJ/mol at 25 °C
Refractive Index
INDEX OF REFRACTION: 1.4144 @ 20 °C/D; MAX ABSORPTION (ALCOHOL): 216 NM (LOG E= 4.04); SADTLER REF NUMBER: 8350
Rotatable Bond Count
1
RTECS Number
OZ2625000
UNII
9HRB24892H
UN Number
2396;2396;1143;2396;2396
Vapor Density
2.4 (AIR= 1);Relative vapor density (air = 1): 2.41;Relative vapor density (air = 1): 2.42
Vapor Pressure
154.99 mmHg;155 mm Hg @ 25 °C;Vapor pressure, kPa at 20 °C: 4.0;Vapor pressure, kPa at 20 °C: 16
Viscosity
0.49 mPa.s @ 20 °C;0.59 mm2/s at 20 °C
XLogP3
0.7
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