CAS 13965-03-2 Bis(triphenylphosphine)palladium(II) Dichloride

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Bis(triphenylphosphine)palladium(II) Dichloride

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Catalog Number

ACM13965032

Product Name

Bis(triphenylphosphine)palladium(II) Dichloride

Structure

CAS

13965-03-2

Category

Salt

Synonyms

TRANS-BIS-(TRIPHENYLPHOSPHINE)PALLADIUM DICHLORIDE; 13965-03-2; 28966-81-6; AC1L36TY; SC-01002; LS-192238; bis(triphenylphosphine) palladiuml(ii) dichloride; bis(triphenylphosphine) palladium (ii) chloride; FC0823; EINECS 237-744-2;

IUPAC Name

palladium(2+);triphenylphosphane;dichloride;

Molecular Weight

701.904g/mol

Molecular Formula

C36H30Cl2P2Pd;

Canonical SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Cl-].[Pd+2];

InChI

InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2;

InChI Key

YNHIGQDRGKUECZ-UHFFFAOYSA-L;

Application

Precatalyst for the carbonylative cyclization of malonate derivatives.

Catalyst used in the double allylation of activated olefins.

Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans.

Precatalyst for the homocoupling of terminal alkynes.

Precatalyst in the cross-coupling of alkynylsilanols and aryl halides.

Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles.

Catalyst for a tandem Heck reaction/C-H functionalization.

Catalyst for direct arylation of tautomerizable heterocycles.

Storage

Store below +30°C.

Complexity

202

Covalently-Bonded Unit Count

EC Number

237-744-2

Exact Mass

700.023g/mol

Heavy Atom Count

Monoisotopic Mass

700.023g/mol