Catalog Number
ACM13965032
Product Name
Bis(triphenylphosphine)palladium(II) Dichloride
Synonyms
TRANS-BIS-(TRIPHENYLPHOSPHINE)PALLADIUM DICHLORIDE; 13965-03-2; 28966-81-6; AC1L36TY; SC-01002; LS-192238; bis(triphenylphosphine) palladiuml(ii) dichloride; bis(triphenylphosphine) palladium (ii) chloride; FC0823; EINECS 237-744-2;
IUPAC Name
palladium(2+);triphenylphosphane;dichloride;
Molecular Weight
701.904g/mol
Molecular Formula
C36H30Cl2P2Pd;
Canonical SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Cl-].[Pd+2];
InChI
InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2;
InChI Key
YNHIGQDRGKUECZ-UHFFFAOYSA-L;
Application
Precatalyst for the carbonylative cyclization of malonate derivatives.
Catalyst used in the double allylation of activated olefins.
Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans.
Precatalyst for the homocoupling of terminal alkynes.
Precatalyst in the cross-coupling of alkynylsilanols and aryl halides.
Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles.
Catalyst for a tandem Heck reaction/C-H functionalization.
Catalyst for direct arylation of tautomerizable heterocycles.
Storage
Store below +30°C.
Covalently-Bonded Unit Count
5
Monoisotopic Mass
700.023g/mol
Topological Polar Surface Area
0A^2