CAS 106294-60-4 (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate

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(2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate

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Catalog Number

ACM106294604-2

Product Name

(2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate

Structure

CAS

106294-60-4

Category

Organic Light-Emitting Diode (OLED) Materials

Synonyms

[Ir(ppy)2(bpy)]PF6 (2,2'-Bipyridine-κN1,κN1')bis[2-(2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate

Description

Alfa Chemistry offers (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate products for various research purposes. Please contact us by email if you do not find the specification you are looking for on this page.

IUPAC Name

iridium(3+);2-phenylpyridine;2-pyridin-2-ylpyridine;hexafluorophosphate

Molecular Weight

801.75

Molecular Formula

C32H24F6IrN4P

Canonical SMILES

C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.F[P-](F)(F)(F)(F)F.[Ir+3]

InChI

InChI=1S/2C11H8N.C10H8N2.F6P.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-7(2,3,4,5)6;/h2*1-6,8-9H;1-8H;;/q2*-1;;-1;+3

InChI Key

RJJGJTKSOSSNNL-UHFFFAOYSA-N

Melting Point

250 °C

Purity

>90.0%(HPLC)

Appearance

Light yellow to Brown powder to crystal

Application

It can be used as a solar energy source.

Storage

Store under inert gas

Complexity

711

Composition

(Nitrogen) 6.00 to 8.00 %

Covalently-Bonded Unit Count

Exact Mass

802.1272g/mol

Features And Benefits

These transition metal complexes are useful photocatalysts, because they can form a long-lived triplet-excited state under photoirradiation. A chemical modification of the coordinating ligands controls the redox potentials of the transition metal complexes.

Formal Charge

Hazard Statements

H315 : Causes skin irritation.H319 : Causes serious eye irritation.

Heavy Atom Count

MDL Number

MFCD04039766

Monoisotopic Mass

802.1272g/mol

Precautionary Statements

P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.

Rotatable Bond Count

Signal Word

Warning

Storage Conditions

Store at room temperature and dry

MSDS

Download MSDS

COA

Download COA

Spec Sheet

Download Spec Sheet

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