CAS 24850-33-7 Allyltributyltin - Materials / Alfa Chemistry

NAVIGATION

Allyltributyltin

PRICE INQUIRY

Catalog Number

ACM24850337-1

CAS Number

24850-33-7

Product Name

Allyltributyltin

Category

Salt

Synonyms

ALLYLTRIBUTYLSTANNANE;ALLYLTRIBUTYLTIN;ALLYLTRIBUTYLTIN(IV);ALLYLTRI-N-BUTYLTIN;TRIBUTYL-2-PROPENYLSTANNANE;Stannane, tributyl-2-propenyl-;Allytri-N-Butyltin;Allyltri-n-butyltin,97%

IUPAC Name

tributyl(prop-2-enyl)stannane

Molecular Weight

331.1g/mol

Molecular Formula

C15H32Sn

Canonical SMILES

CCCC[Sn](CCCC)(CCCC)CC=C

InChI

InChI=1S/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;3H,1-2H2;

InChI Key

YLGRTLMDMVAFNI-UHFFFAOYSA-N

Purity

>95.0%(GC)

Application

Allyltributyltin is a clear, colorless liquid designed primarily for the selective allylation of aldehydes. In the presence of chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate, it acts as an efficient reagent to convert aldehydes into homoallylic alcohols. Additionally, it can undergo coupling reactions with iodoquinones and allyl acetates when catalyzed by tetrakis(triphenylphosphine)palladium(0), making it a versatile tool in organic synthesis.

Complexity

141

Covalently-Bonded Unit Count

EC Number

246-494-3

Exact Mass

332.152603g/mol

Formal Charge

Heavy Atom Count

Monoisotopic Mass

332.152603g/mol

Rotatable Bond Count