CAS 14874-82-9 (Acetylacetonato)dicarbonylrhodium(I)

NAVIGATION

(Acetylacetonato)dicarbonylrhodium(I)

PRICE INQUIRY

Catalog Number

ACM14874829-3

CAS Number

14874-82-9

Product Name

(Acetylacetonato)dicarbonylrhodium(I)

Structure

Category

Solution Deposition Precursors

Synonyms

Acetylacetonatodicarbonylrhodium;Acetylacetonatorhodium dicarbonyl;Dicarbonyl-(2,4-pentandione)-rhodium;Dicarbonyl(2,4-pentanedionato)rhodium;Dicarbonylacetylacetonatorhodium;Dicarbonylrhodium acetylacetonate;Rhodium dicarbonylacetylacetonate;Rhodium, dic

Molecular Weight

258.03

Molecular Formula

Rh(CO)2(C5H7O2)

Melting Point

154-156 °C(lit.)

Purity

98%

Application

(Acetylacetonato)dicarbonylrhodium(I) serves as a versatile catalyst in a range of chemical reactions, significantly enhancing the efficiency of processes such as carbonylation, silylcarbocyclizations, and conjugate additions to enones. This compound, characterized by its red/green crystalline powder form, is part of Umicore's line of precatalysts specifically designed for asymmetric and cross-coupling catalysis. It plays a crucial role as a precatalyst in hydroformylation and silylformylation of olefins, as well as in carbonylative silylcarbocyclization during the synthesis of complex molecules like isodomoic acids. Additionally, it facilitates the conjugate addition of aryl- and alkenylboronic acids to enones, and is effective in the carbamoylstannation and reduction of aromatic nitro compounds, highlighting its wide applicability and importance in synthetic chemistry.

Hazard Statements

H301-H315-H317-H319-H335

MDL Number

MFCD00009884

Safety Description

Danger

UN Number

UN 3467 6.1 / PGIII

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