CAS 152329-44-7 (2-Naphthylmethyl)zinc bromide solution

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(2-Naphthylmethyl)zinc bromide solution

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Catalog Number

ACM152329447-1

CAS Number

152329-44-7

Product Name

(2-Naphthylmethyl)zinc bromide solution

Structure

Category

Salt

IUPAC Name

bromozinc(1+);2-methanidylnaphthalene

Molecular Weight

286.5g/mol

Molecular Formula

C11H9BrZn

Canonical SMILES

[CH2-]C1=CC2=CC=CC=C2C=C1.[Zn+]Br

InChI

InChI=1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q-1;;+2/p-1

InChI Key

RZWMNWMGKBGIQX-UHFFFAOYSA-M

Application

The (2-Naphthylmethyl)zinc bromide solution serves as a versatile reagent in organic synthesis, effectively facilitating the formation of complex compounds. It is used in the synthesis of 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile by reacting with 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile in the presence of a palladium catalyst. Additionally, it aids in the construction of (E)-stilbene, specifically (2,2'-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]), from 1,4-benzenedicarboxaldehyde, utilizing a palladium catalyst and a silylating agent. This reagent's reactivity and compatibility with palladium-catalyzed processes make it a valuable tool in the synthesis of complex organic molecules.

Complexity

138

Covalently-Bonded Unit Count

Exact Mass

283.9179g/mol

Formal Charge

Heavy Atom Count

Monoisotopic Mass

283.9179g/mol

Rotatable Bond Count

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