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  • (2-Naphthylmethyl)zinc bromide solution

  • (2-Naphthylmethyl)zinc bromide solution

    Catalog Number
    ACM152329447-1
    CAS Number
    152329-44-7
    Product Name
    (2-Naphthylmethyl)zinc bromide solution
    Category
    Salt
    IUPAC Name
    bromozinc(1+);2-methanidylnaphthalene
    Molecular Weight
    286.5g/mol
    Molecular Formula
    C11H9BrZn
    Canonical SMILES
    [CH2-]C1=CC2=CC=CC=C2C=C1.[Zn+]Br
    InChI
    InChI=1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q-1;;+2/p-1
    InChI Key
    RZWMNWMGKBGIQX-UHFFFAOYSA-M
    Application
    The (2-Naphthylmethyl)zinc bromide solution serves as a versatile reagent in organic synthesis, effectively facilitating the formation of complex compounds. It is used in the synthesis of 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile by reacting with 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile in the presence of a palladium catalyst. Additionally, it aids in the construction of (E)-stilbene, specifically (2,2'-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]), from 1,4-benzenedicarboxaldehyde, utilizing a palladium catalyst and a silylating agent. This reagent's reactivity and compatibility with palladium-catalyzed processes make it a valuable tool in the synthesis of complex organic molecules.
    Complexity
    138
    Covalently-Bonded Unit Count
    2
    Exact Mass
    283.9179g/mol
    Formal Charge
    0
    Heavy Atom Count
    13
    Monoisotopic Mass
    283.9179g/mol
    Rotatable Bond Count
    0
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