CAS 864163-80-4 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate

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(2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate

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Catalog Number

ACM864163804

Product Name

(2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate

Structure

CAS

864163-80-4

Category

Organic Light-Emitting Diode (OLED) Materials

Synonyms

Ir[(dFppy)2(bpy)]PF6

Description

Alfa Chemistry offers (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate products for various research purposes. Please contact us by email if you do not find the specification you are looking for on this page.

IUPAC Name

2-(2,4-difluorophenyl)pyridine;iridium(3+);2-pyridin-2-ylpyridine;trihexafluorophosphate

Molecular Weight

873.71

Molecular Formula

C32H20F10IrN4P

Canonical SMILES

C1=CC=NC(=C1)C2=C(C=C(C=C2)F)F.C1=CC=NC(=C1)C2=C(C=C(C=C2)F)F.C1=CC=NC(=C1)C2=CC=CC=N2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ir+3]

InChI

InChI=1S/2C11H6F2N.C10H8N2.F6P.Ir/c2*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-7(2,3,4,5)6;/h2*1-4,6-7H;1-8H;;/q2*-1;;-1;+3

InChI Key

BWQRXIXHHHVGJD-UHFFFAOYSA-N

Melting Point

327 °C

Purity

>80.0%(HPLC)

Appearance

Light yellow to Brown powder to crystal

Application

It can be used as a solar energy source.

Storage

Store under inert gas

Complexity

369

Composition

(Nitrogen) 6.00 to 6.75 %

Covalently-Bonded Unit Count

Exact Mass

1166.03353g/mol

Features And Benefits

These transition metal complexes are useful photocatalysts, because they can form a long-lived triplet-excited state under photoirradiation. A chemical modification of the coordinating ligands controls the redox potentials of the transition metal complexes.

Formal Charge

Hazard Statements

H315 : Causes skin irritation.H319 : Causes serious eye irritation.

Heavy Atom Count

MDL Number

MFCD12022466

Monoisotopic Mass

1166.03353g/mol

Precautionary Statements

P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.

Rotatable Bond Count

Signal Word

Warning

Storage Conditions

Store at room temperature and dry

MSDS

Download MSDS

COA

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Spec Sheet

Download Spec Sheet

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