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1,1,4,7,10,10-Hexamethyltriethylenetetramine

Catalog NumberACM3083101-1

CAS Number3083-10-1

CategoryPolymerization Reagents

1,1,4,7,10,10-Hexamethyltriethylenetetramine
Synonyms
HMTETA
Description
1,1,4,7,10,10-Hexamethyltriethylenetetramine is a polyamines additive, has been reported as an efficient reagent for the problematic Koenigs-Knorr glucuronidation.
IUPAC Name
N'-[2-[2-(dimethylamino)ethyl-methylamino]ethyl]-N,N,N'-trimethylethane-1,2-diamine;
Molecular Weight
230.39
Molecular Formula
[(CH3)2NCH2CH2N(CH3)CH2-]2
Canonical SMILES
CN(C)CCN(C)CCN(C)CCN(C)C
InChI
1S/C12H30N4/c1-13(2)7-9-15(5)11-12-16(6)10-8-14(3)4/h7-12H2,1-6H3
InChI Key
DWFKOMDBEKIATP-UHFFFAOYSA-N
Boiling Point
130 °C/11 mmHg (lit.)
Flash Point
215.6 °F - closed cup
Purity
97%
Density
0.847 g/mL at 25 °C (lit.)
Appearance
Colorless to Light orange to Yellow clear liquid
Application
1,1,4,7,10,10-Hexamethyltriethylenetetramine may be used as reagent in the synthesis of ideal linear random copolymers containing both vinyl polymer and polyester units in a single polymer chain. 1,1,4,7,10,10-Hexamethyltriethylenetetramine complexed with CuBr constitutes catalytic complex, used in the copolymerization of poly[ε-caprolactone] with N,N-dimethylamino-2-ethyl methacrylate monomers by atom-transfer radical polymerization (ATRP). It may be used as catalyst in the aqueous surface-initiated-ATRP to grow poly(N,N-dimethylacrylamide) (PDMA).
Assay
97%
Complexity
141
Covalently-Bonded Unit Count
1
EC Number
221-382-7
Exact Mass
230.247g/mol
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Heavy Atom Count
16
MDL Number
MFCD00025684
Monoisotopic Mass
230.247g/mol
NSC Number
166488
Packaging
Packaging
5, 25 g in glass bottle
Refractive Index
n20/D 1.456 (lit.)
Rotatable Bond Count
9
Topological Polar Surface Area
13A^2
UNII
0OAF7T9SCQ
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