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Sodium sulfate

Catalog Number
ACM7757826
Product Name
Sodium sulfate
Structure
CAS
7757-82-6
Category
Electrolytes
Synonyms
Disodium sulfate
Description
Sodium sulfate is the inorganic compound with formula Na2SO4 as well as several related hydrates. All forms are White solids that are highly soluble in water. With an annual production of 6 million tonnes, the decahydrate is a major commodity chemical product. It is mainly used for the manufacture of detergents and in the Kraft process of paper pulping.
IUPAC Name
Disodium;sulfate
Molecular Weight
142.04
Molecular Formula
Na2O4S
Canonical SMILES
[O-]S(=O)(=O)[O-].[Na+].[Na+]
InChI
InChI=1S/2Na.H₂O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q2*+1;/p-2
InChI Key
PMZURENOXWZQFD-UHFFFAOYSA-L
Boiling Point
1700 °C
Melting Point
884 °C
Purity
99%+
Density
2.68 g/mL at 25 °C (lit.)
Solubility
Soluble in glycerin, insoluble in alcohol
Appearance
White powder
Storage
Store at +5 °C to +30 °C
Color/Form
Powder or orthorhombic bipyramidal crystals;White orthorhombic crystals or powder
Complexity
62.2
Corrosivity
The rates of corrosion of iron and steel in water are a function of the specific mineral quality as well as the alkalinity and pH values. Sodium sulfate ... is a strong contributor to the rate of corrosion. For example, in water with 400 mg/l of alkalinity (as CaCO3) at pH 7, the corrosion rate will be zero at 200 mg/l of Na2SO4, but when the concentration of sodium sulfate is 400 mg/l, the corrosion rate will be about 100 mg per square cm per day.
Covalently-Bonded Unit Count
3
EC Number
231-820-9;268-366-6;268-773-9;270-211-2
Exact Mass
141.93126821
Formal Charge
0
Heavy Atom Count
7
ICSC Number
0952
Log P
-0.25720
MeSH Entry Terms
disodium sulfate;mangxiao;mirabilitum;natrii sulphas;puxiao;sodium bisulfate;sodium bisulfate, monohydrate;sodium hydrosulfate;sodium sulfate;sodium sulfate, 35S-labeled cpd;sodium sulfate, decahydrate;sulfuric acid, monosodium salt;thenardite
Monoisotopic Mass
141.93126821
Odor
Odorless
Other Experimental
Transition point to anhydrous form is 24.4 °C; white, rhombic or tetragonal; 19.5 g/100 cc water at 0 °C, 44 g/100 cc water at 20 °C/Sodium sulfate heptahydrate/;Density: 1.46; loses all its water at 100 °C; efflorescent crystals or granules; odorless; aqueous solution is neutral; pH 6 to 7.5; soluble in 1.5 parts water at 25 °C, in 3.3 parts water at 15 °C (solubility in water decreased by sodium chloride); soluble in glycerol; insoluble in alcohol /Sodium sulfate decahydrate/;Transparent, monoclinic crystals; mp: 32.38 °C; index of refraction: 1.394, 1.396, 1.398 /Sodium sulfate decahydrate/;Objectionable taste /Sodium sulfate decahydrate/;4.76 g/100 cc water at 0 °C, 42.7 g/100 cc water at 100 °C; soluble in glycerol; insoluble in alcohol; index of refraction: 1.484, 1.477, 1.471 /Natural thenardite/;Latent heat of fusion: 24.4 kJ at melting point;Heat of formation: -1385 Kj/mole;Entropy: 149.6 J/(mole x K);Heat of solution: 1.17 kJ/mole
Refractive Index
1.484
Rotatable Bond Count
0
RTECS Number
WE1650000
Stability
Stable. Incompatible with strong acids, aluminium, magnesium, strong bases. Hygroscopic.
Storage Conditions
Store at RT.
Topological Polar Surface Area
88.6 Ų
UNII
36KCS0R750
Vapor Pressure
3.35E-05mmHg at 25°C
Viscosity
2.48 (22% solution at 20 °C)
WGK Germany
1
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