NAVIGATION


Samarium

Catalog Number
ACMA00014366
Product Name
Samarium
Category
Glass Additives
IUPAC Name
samarium
Molecular Weight
150.4g/mol
Molecular Formula
Sm
Canonical SMILES
[Sm]
InChI
InChI=1S/Sm
InChI Key
KZUNJOHGWZRPMI-UHFFFAOYSA-N
Boiling Point
1794 °C
Melting Point
1072 °C
Density
7.52 g cu cm at 25 °C
Application
Samarium is a versatile element with various applications, primarily due to its properties as a neutron absorber and its role as a component in advanced materials. In chemical reactions, samarium, when combined with titanium(IV) chloride, effectively reduces arylsulfonyl chlorides and arylsulfinates to form diaryl disulfides. This soft, silvery-grey metallic element, belonging to the lanthanoids, is notable for its use in special alloys essential for nuclear reactor parts due to its neutron-absorbing capabilities. Additionally, samarium is employed as a dopant in laser crystals and in producing ferromagnetic alloys, like SmCo5, which yield exceptionally strong permanent magnets. Furthermore, samarium oxide finds applications in special optical glasses. First discovered by François Lecoq de Boisbaudran in 1879, samarium continues to be pivotal in various technological advancements.
Color/Form
Silvery metal; rhombohedral
Complexity
0
Covalently-Bonded Unit Count
1
EC Number
231-128-7
Exact Mass
151.91974g/mol
Formal Charge
0
Heavy Atom Count
1
MeSH Entry Terms
Samarium
Monoisotopic Mass
151.91974g/mol
Other Experimental
Samarium has high thermal neutron capture cross section ... has a low rate of burn off when used in control rods or in ceramics for radiation protection;Reasonably stable in air;Three crystal modifications of the metal exit, eith transformations at 734 and 922 °C;Ignites in air at 150 °C;Specific heat capacity at 298 K, J-mol/K: 29.6; linear coefficient of expansion, 10-6/K: 10.4; thermal conductivity W/cm/K: 0.133; Vickers hardness: 45; Modulus of elasticity, 10+10 N/sq m: 5.75; Shear modulus, 10+10 N/sq m:1.26;Poisson's ratio: 0.352; Grueneisen constant for temperature dependence of electrical resistivity: 0.63; Electrical resistivity, microohlm/cm: 94; Electrion emission, eV: 2.7-2.8; crystal structure of stable phase at room temperature; Lattice constants, nm: 0.3621 (a); 2.625 (c); Distillation rate: 83 g-sq cm/hr at 1.3X10-3 bar;33 isotopes and isomers of samarium ... natural samarium is a mixture of seven isotopes, three of which are unstable but have long half-lives;Samarium-147 and -148 are naturally occurring and stable. Samarium-129 through -143 and samarium-155 through -162 are artificially produced and are radioactive.
Rotatable Bond Count
0
UNII
42OD65L39F
Vapor Pressure
1.3X10-5 bar at 722 mm Hg; 1.3X10-3 bar at 964 mm Hg
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