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  • Poly(vinyl alcohol) 105,

  • Poly(vinyl alcohol) 105,

    Catalog Number
    ACM9002895-16
    CAS Number
    9002-89-5
    Product Name
    Poly(vinyl alcohol) 105,
    Structure
    Category
    Polymers
    Description
    Polyvinyl alcohol appears as odorless white to cream-colored granules or powder. Pure aqueous solutions are neutral or faintly acid and subject to mold growth. pH (4% aqueous solution): 5-8. Strongly hydrophilic. (NTP, 1992);Odourless, tasteless, translucent, white or cream-coloured granular powder;COLOURLESS-TO-WHITE SOLID IN VARIOUS FORMS.
    IUPAC Name
    ethenol
    Molecular Weight
    44.05g/mol
    Molecular Formula
    (C2H3OR)nwhere R = H or COCH3;(CH2CHOH-)n;CH2CHOH;C2H4O
    Canonical SMILES
    C=CO
    InChI
    InChI=1S/C2H4O/c1-2-3/h2-3H,1H2
    InChI Key
    IMROMDMJAWUWLK-UHFFFAOYSA-N
    Boiling Point
    644 °F at 760 mm Hg approximately (NTP, 1992);644 °F at 760 mm Hg /approximately/
    Melting Point
    442 °F (decomposes) (NTP, 1992);>200 °C; other melting points: 212-267 °C
    Flash Point
    175 °F (NTP, 1992);175 °F (79 °C) (open cup);79 °C o.c.
    Density
    1.329 (NTP, 1992);1.91 to 1.31;1.19-1.31 g/cm³
    Solubility
    Soluble (NTP, 1992);Soluble in water; sparingly soluble in ethanol;Soluble in water;Solubility in water: good;Water solubility increases as molecular weight decreases;Slightly soluble in ethanol, but insoluble in other organic solvents;Essentially soluble in hot and cold water, but those coded 20-105 require alcohol-water mixtures; Insoluble in petroleum solvents;Practically insoluble in animal and vegetable oils; insoluble in aromatic hydrocarbons, esters, ether, acetone; practically insoluble in chlorinated hydrocarbons;Solubility in water: good
    Application
    Poly(vinyl alcohol) 105, a versatile and odorless white to cream-colored granular powder, serves multiple purposes across various fields. It is primarily utilized as a pharmaceutic aid and ophthalmic lubricant, prominently in the formulation of topical pharmaceutical and ophthalmic products, where it enhances viscosity and stability. This tough polymer can be crafted into strong films, tubes, and fibers resistant to hydrocarbon solvents, extending its use to the manufacturing of surface coatings, artificial sponges, and cosmetics. Additionally, it plays a role in drug delivery, surface-enhanced Raman spectroscopy (SERS) fiber-optic sensors, and the production of transparent conducting oxides (TCOs). Its unique properties allow it to be water-soluble, though it can be rendered insoluble through processes such as drawing or cross-linking, broadening its application to include artificial tears, contact lens solutions, sustained-release oral formulations, and transdermal patches.
    Color/Form
    Dry, unplasticized powders are white or cream colored;Colorless, white or cream, amorphous powder
    Complexity
    10.3
    Covalently-Bonded Unit Count
    1
    EC Number
    209-183-3;618-340-9
    Exact Mass
    44.026215g/mol
    Formal Charge
    0
    Heavy Atom Count
    3
    ICSC Number
    1489
    MeSH Entry Terms
    Alcohol, Polyvinyl;Liquifilm Tears;Polyvinyl Alcohol;Polyviol;Tears, Liquifilm
    Monoisotopic Mass
    44.026215g/mol
    NSC Number
    108129
    Odor
    Odorless
    Other Experimental
    Polymer average molecular weight: 120,000;Softens at about 200 °C with decomposition;Subject to mold growth;Decomposes at 228 °C;Undergoes chemical reactions typical of compound with secondary hydroxyl groups, including esterification and etherification;Strength, elongation, tear resistance, and flexibility improve with increasing molecular weight;Tensile strength up to 22,000 psi
    Refractive Index
    Index of refraction: 1.49-1.53
    Rotatable Bond Count
    0
    RTECS Number
    TR8100000
    Stability
    Stable under recommended storage conditions.
    Vapor Pressure
    Negligible (NTP, 1992);Negligible
    Viscosity
    /p>4,8 to 5,8 mPa.s (4 % solution at 20 °C) corresponding to an average molecular weight of 26 000-30 000 Da
    XLogP3
    0.5
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