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Poly(dimethylsiloxane)

Catalog Number
ACM107517-1
Product Name
Poly(dimethylsiloxane)
Structure
CAS
107-51-7
Category
Salt
Synonyms
Octamethyltrisiloxane
Description
Poly(dimethylsiloxane) (PDMS), also known as dimethicone, is an organosilicon compound that is widely used as a siloxane based elastomer. It is a hydrophobic material with attractive physical and chemical properties such as elasticity, optical transparency, tunable surface chemistry, and low electrical conductivity.
IUPAC Name
dimethyl-bis(trimethylsilyloxy)silane
Molecular Weight
236.53
Molecular Formula
[(CH3)3SiO]2Si(CH3)2
Canonical SMILES
C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C
InChI
1S/C8H24O2Si3/c1-11(2,3)9-13(7,8)10-12(4,5)6/h1-8H3
InChI Key
CXQXSVUQTKDNFP-UHFFFAOYSA-N
Boiling Point
153 °C (lit.)
Melting Point
-82 °C (lit.)
Density
0.82 g/mL at 25 °C (lit.)
Solubility
1.44e-07 M;Immiscible with water;Immiscible with alcohol;Miscible with chloroform; soluble in chlorinated hydrocarbons, benzene, toluene, xylene, n-hexane, petroleum spirits, ether, amyl acetate; very slightly soluble in isopropyl alcohol; insoluble in methanol, acetone
Color/Form
Colorless oil;Clear colorless liquids
Complexity
149
Covalently-Bonded Unit Count
1
EC Number
203-497-4;613-156-5;618-433-4
Exact Mass
236.10841g/mol
Formal Charge
0
Heavy Atom Count
13
Log P
6.6 (LogP)
MeSH Entry Terms
dimethicone;dimethyl polysiloxane;dimeticone
Monoisotopic Mass
236.10841g/mol
Other Experimental
Silcone oil consisting of dimethylsiloxane polymers range in viscosities from 0.65-1,000,000 centistokes at room temp;Low surface tension, inert /Silicones/;Index of refraction: 1.4013 to 1.4053 at 35 °C; viscosity at 25 °C: 350 cSt; density: 0.965-0.973 /Dimethicone 350/;Viscosity: 41 cSt at 37.8 °C /Silicone fluid with 10 mm sq/S viscosity/;DIMETHYLPOLYSILOXANES ARE PRACTICALLY INERT POLYMERS
Packaging
50 mL in glass bottle
Refractive Index
n20/D 1.384 (lit.)
Rotatable Bond Count
4
Stability
Stable to heat and ... resistant to most chemical substances, although they are affected by strong acids.
UNII
9G1ZW13R0G
Vapor Density
Pour point -73 °C; Electric Strength 1.4 KV/um; Electric Constant 2.60; Thermal conductivity at 65 °C = 1.3 W/(m.k). /Silicone fluid with 10 mm sq/5 viscosity/
Vapor Pressure
3.34 mmHg
Viscosity
1.0 cSt(25 °C)
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