CAS 161265-03-8 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene

NAVIGATION

4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene

PRICE INQUIRY

Catalog Number

ACM161265038-2

CAS Number

161265-03-8

Product Name

4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene

Structure

Category

Polymerization Reagents

IUPAC Name

(5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl)-diphenylphosphane

Molecular Weight

578.6g/mol

Molecular Formula

C39H32OP2

Canonical SMILES

CC1(C2=C(C(=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)OC5=C1C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7)C

InChI

InChI=1S/C39H32OP2/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3

InChI Key

CXNIUSPIQKWYAI-UHFFFAOYSA-N

Application

4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene is an organophosphorus compound derived from the heterocycle xanthene, serving as a versatile bidentate ligand distinguished by its notably wide bite angle. Its primary purpose is to facilitate a wide array of catalytic transformations, which include hydroformylation, cross couplings, and various Pd, Cu, Rh, Ru, and Au-catalyzed reactions. This ligand plays a crucial role in enhancing reaction efficiency and selectivity, making it particularly valuable in the synthesis of complex organic compounds. Its utility extends across diverse applications such as the coupling of amides and hydrazones with aryl halides, hydrophosphinylation of alkenes and alkynes, sulfinylation, carbonylation, dehydrogenative silation, and the assembly of heterocycles. Whether used for direct arylation, decarboxylative coupling, or difunctionalization processes, this ligand is essential for advancing modern catalytic methodologies in organic chemistry.

Complexity

731

Covalently-Bonded Unit Count

EC Number

605-249-4

Exact Mass

578.19284g/mol

Formal Charge

Heavy Atom Count

MeSH Entry Terms

9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene;xantphos

Monoisotopic Mass