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Ammonium thiosulfate

Catalog Number
ACM7783188
CAS Number
7783-18-8
Product Name
Ammonium thiosulfate
Structure
Category
Electrolytes
Description
Ammonium thiosulfate is a white crystalline solid. It is very soluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. It is used in photography, in chemical analysis, and for many other uses.;Liquid
IUPAC Name
diazanium;dioxido-oxo-sulfanylidene-ж╦6-sulfane
Molecular Weight
148.21g/mol
Molecular Formula
H8N2O3S2
Canonical SMILES
[NH4+].[NH4+].[O-]S(=O)(=S)[O-]
InChI
InChI=1S/2H3N.H₂O3S2/c;;1-5(2,3)4/h2*1H3;(H2,1,2,3,4)
InChI Key
XYXNTHIYBIDHGM-UHFFFAOYSA-N
Boiling Point
Decomposes (NTP, 1992)
Melting Point
Decomposes at 302° F (NTP, 1992);150 °C (DECOMP)
Purity
98%
Density
2 at 68 °F (USCG, 1999);1.679
Solubility
64 % at 68° F (NTP, 1992);VERY SOL IN COLD WATER; IN 100 CC OF WATER: 103.3 G @ 100 °C; SLIGHTLY SOL IN ACETONE;INSOL IN ALCOHOL, ETHER
Appearance
Solid
Application
Ammonium thiosulfate serves multiple purposes across various industries. Primarily, it is used as a liquid fertilizer due to its high nitrogen and sulfur content, which supports plant growth by decomposing into ammonium sulfate and colloidal sulfur upon application. This decomposition ensures that the ammonium sulfate is immediately available as a nutrient, while the sulfur oxidizes over time to provide a sustained release of nutrients. Additionally, ammonium thiosulfate acts as a urease inhibitor, prolonging the availability of nitrogen when used in combination with urea-ammonium nitrate solutions. Beyond agriculture, it functions as a photographic fixing agent, an analytical reagent, a fungicide, and a brightener in silver-plating baths, capitalizing on its unique chemical properties. This crystalline salt, characterized by its ammonia odor, is soluble in water and non-corrosive, making it suitable for storage in steel or aluminum containers. Its compatibility with nitrogen and nitrogen-potassium solutions enhances its versatility.
Color/Form
COLORLESS, MONOCLINIC CRYSTALS;WHITE CRYSTALS
Complexity
82.6
Corrosivity
Copper-base alloys are seriously corroded by ... ammonium thiosulfate with corrosion rates exceeding 10 kg/(square meter year) at 100 °C.;High silicon cast iron has reasonable corrosion resistance /to ammonium thiosulfate/ with a corrosion rate < 4.4 kg/(square meter year) at 100 °C.;The corrosion rate for stainless steels /to ammonium thiosulfate/ is < 440 g/(square meter year) at 100 °C.
Covalently-Bonded Unit Count
3
EC Number
231-982-0
Exact Mass
147.997634g/mol
Formal Charge
0
Heavy Atom Count
7
MeSH Entry Terms
ammonium thiosulfate
Monoisotopic Mass
147.997634g/mol
Odor
AMMONIA ODOR
Other Experimental
Hygroscopic;No hydrates /of ammonium thiosulfate/ are known.
Rotatable Bond Count
0
Stability
Solutions decompose slowly below 50 °C and more rapidly at higher temperatures. The anhydrous salt decomposes above 100 °C to sulfite and sulfur.
UNII
BKH1729645
Vapor Pressure
0 mm Hg (NTP, 1992)
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