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  • 2-(Nonafluorobutyl)ethyl methacrylate

    Catalog Number
    ACM1799844
    CAS Number
    1799-84-4
    Product Name
    2-(Nonafluorobutyl)ethyl methacrylate
    Structure
    Category
    Monomers
    Synonyms
    2-(Nonafluorobutyl)ethyl methacrylate;2-(Perfluorobutyl)ethyl methacrylate
    IUPAC Name
    3,3,4,4,5,5,6,6,6-nonafluorohexyl 2-methylprop-2-enoate
    Molecular Weight
    332.16g/mol
    Molecular Formula
    C10H9F9O2
    Canonical SMILES
    CC(=C)C(=O)OCCC(C(C(C(F)(F)F)(F)F)(F)F)(F)F
    InChI
    InChI=1S/C10H9F9O2/c1-5(2)6(20)21-4-3-7(11,12)8(13,14)9(15,16)10(17,18)19/h1,3-4H2,2H3
    InChI Key
    TYNRPOFACABVSI-UHFFFAOYSA-N
    Density
    1.377g/cm³
    Complexity
    411
    Covalently-Bonded Unit Count
    1
    EC Number
    217-287-5
    Exact Mass
    332.045883g/mol
    Formal Charge
    0
    Heavy Atom Count
    21
    Monoisotopic Mass
    332.045883g/mol
    Rotatable Bond Count
    7
    XLogP3
    4.6
    Case Study

    RAFT Dispersion Polymerization of 2-(Nonafluorobutyl)ethyl Methacrylate in Ethanol

    Huo M, et al. Macromolecular Rapid Communications, 2018, 39(7): 1700840.

    Alcoholic reversible addition-fragmentation chain-transfer (RAFT) dispersion polymerization of 2-(perfluorobutyl)ethyl methacrylate (FBEMA) extends the general availability of semifluorinated methacrylates to polymerization-induced self-assembly (PISA).
    · The monomer conversion reaches 90% within 11 h, while the corresponding semi-logarithmic plot shows two distinct regimes: the rate of polymerization is relatively slow for the first 3 h, while a dramatic increase in the rate is observed in the following 8 h (Figure 1a).
    · Both the two regimes of the curve represent pseudo-first kinetics, suggesting good control of the RAFT polymerization.
    · Mn of these block copolymers increases with the monomer conversion, and the dispersities are <1.30 for all the copolymers (Figure 1c).

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