All about MXenes Materials

MXenes are a new type of two-dimensional transition metal carbides, nitrides or carbonitrides. With their unique two-dimensional structure, tunable properties and multifunctionality, MXenes have become a research hotspot in the field of materials science and are expected to achieve breakthrough applications in energy, electronics, environment and other fields in the future.

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  • Definition
  • Features
  • Products
  • Applications
  • Qualifications
  • FAQs
  • Case Study
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What is MXenes Material?

The general chemical formula of MXenes is Mn+1XnTx. Among them: M is an early transition metal (such as Ti, V, Nb, Mo, etc.); X is carbon (C) or nitrogen (N); Tx represents a surface termination group (such as -O, -OH, -F, -Cl, etc.). MXenes is a material composed of two-dimensional transition metal carbides and nitrides, obtained by selectively etching the A element from the MAX phase.

What are the Features of Magnetic Beads?

High Conductivity

MXenes have electrical conductivity close to that of metals, for example, the conductivity of MXenes thin films reaches 4600 S/cm), making them suitable for electronic devices and electrode materials.

Hydrophilicity and Mechanical Properties

The surface termination groups give MXenes hydrophilicity, while their nanosheet structure provides excellent flexibility and mechanical strength, for example, the tensile strength is significantly improved after being compounded with polymers.

Adjustable Properties

The electronic structure, optical properties and chemical activity of MXenes can be precisely adjusted through solid solution design (such as mixing M-site or X-site elements) and surface termination group regulation. ‌

MXenes Materials Products List

What are the Applications of MXenes Materials?

Energy Storage

MXenes' high volumetric capacitance and rapid ion intercalation make them high-performance electrode materials. MXenes also exhibit high capacity and catalytic activity as negative electrodes for lithium/sodium ion batteries or as catalyst carriers for hydrogen production from water electrolysis.

Electromagnetic Shielding

MXenes' conductive network and multi-layer reflection mechanism enable them to achieve shielding effectiveness of >50 dB at ultra-thin thicknesses (e.g., 2.5 μm), which is superior to most synthetic materials.

Sensors and Catalysis

The rich active sites on the surface can be used for gas sensing, electrochemical detection, and photocatalysis.

Environment and Biomedicine

MXenes' adsorption capacity is suitable for water purification, and their near-infrared absorption properties can also be used for photothermal therapy

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Question and Answer

What is the difference between MXene and graphene?

Although MXene and graphene share their classification as two-dimensional materials they exhibit important variations in their structural composition and practical applications. Graphene represents a pure carbon substance made up of carbon atoms bonded in sp² hybridization. MXene contains transition metal carbides/nitrides.

While graphene offers excellent conductivity it suffers a substantial decrease after oxidation; MXene exhibits metallic conductivity combined with hydrophilicity along with stable and controllable surface functional groups. While both materials serve purposes in energy storage and electromagnetic shielding graphene dominates flexible electronics and coatings because it is mature but MXene excels in biomedicine and anti-corrosion coatings because of its biocompatibility and surface activity.

How to select MXene materials?

MXene can be selected based on performance requirements to maximize its application potential. Select MXene with matching properties according to the target field (such as energy storage, sensing, catalysis, etc.). For example, energy storage requires high conductivity (~10⁵ S/m) and adjustable interlayer spacing to facilitate ion transport, while sensors require controllable modification of surface functional groups (-OH, -F, etc.) to optimize sensitivity.

How to preserve MXene materials?

The preservation of MXene materials needs to take into accounts its easy oxidation and hygroscopic properties.

The container should be selected to prevent chemical reactions and be clean and dry.

An inert gas environment is required.

Temperature control needs to be under appropriate conditions.

Avoid light to slow down degradation.

In addition, studies have shown that moisture is a key factor in MXene degradation, and the influence of water molecules needs to be isolated.

What are the advantages and disadvantages of MXene materials?

The exceptional conductivity, controllability, mechanical properties and potential applications of MXene materials have made them a center of attention in materials science research. The production process of MXene materials presents unresolved challenges related to safety hazards and high costs along with stability problems.

Case Study

The exciting future of MXenes

Gogotsi, Yury. Chemistry of Materials 35.21 (2023): 8767-8770.

The advancement of MXenes toward industrial applications requires the development of scalable, low-cost, safe, and environmentally friendly synthesis processes, as well as extensive and thorough investigation of their toxicity and fate in the environment. All new materials follow this path. The field of MXenes has a bright and exciting future based on the unique and tunable properties of MXenes, as well as their huge compositional diversity and tunability of properties.

One of the most compelling applications of MXenes is its ability to compete with gold and silver in printed electronics, outperform indium tin oxide (ITO) in flexible and foldable transparent devices, and perform at the level of copper and aluminum in EMI shielding, but allowing the use of films much thinner than metal foil films. It also outperforms gold and graphene in epidermal and implantable electronics due to lower impedance in contact with skin and tissue. Also note that it is room temperature deposited from solution, requiring no vacuum sputtering or high temperature deposition and post-processing. The high breakdown current makes TiC also promising for nano-thin interconnects.

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