CAS 94928-86-6 Tris[2-phenylpyridinato-C2,N]iridium(III), purified by sublimation

NAVIGATION

Tris[2-phenylpyridinato-C2,N]iridium(III), purified by sublimation

PRICE INQUIRY

Catalog Number

ACM94928866-4

CAS Number

94928-86-6

Product Name

Tris[2-phenylpyridinato-C2,N]iridium(III), purified by sublimation

Structure

Category

Sublimed Materials

IUPAC Name

iridium;2-phenylpyridine

Molecular Weight

657.8g/mol

Molecular Formula

C33H27IrN3

Canonical SMILES

C1=CC=C(C=C1)C2=CC=CC=N2.C1=CC=C(C=C1)C2=CC=CC=N2.C1=CC=C(C=C1)C2=CC=CC=N2.[Ir]

InChI

InChI=1S/3C11H9N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-9H;

InChI Key

UEEXRMUCXBPYOV-UHFFFAOYSA-N

Application

Tris[2-phenylpyridinato-C2,N]iridium(III), purified by sublimation, is a versatile compound utilized for its remarkable photocatalytic properties. Its core component, iridium, allows it to function effectively as a catalyst in various chemical reactions. It plays a crucial role in the synthesis of fused-quinoxaline derivatives, difluorinated ketones, and carbazoles. Additionally, this compound serves as a significant modifier in the optogenetic study of behavior in Drosophila melanogaster, specifically in larvae expressing ChR2. In the medical arena, it contributes to the development of metal-containing nucleosides with both therapeutic and diagnostic potential against cancer. Moreover, its high quantum yields and thermal stability make it an essential material in organic light-emitting diodes (OLEDs), offering bright phosphorescence and efficient light emission by leveraging both singlet and triplet excitons. Its applications extend to photoredox reactions, including α-amino C-H arylation of cyano(hetero)arenes, trifluoromethylation of alkenes and alkynes, reduction of various iodides, direct arylation of allylic sp3 C-H bonds, and the generation of multifluorinated biaryls. Consequently, Tris[2-phenylpyridinato-C2,N]iridium(III) stands out as a critical component in both technological and research advancements within photoredox catalysis and OLED display technologies.

Complexity

127

Covalently-Bonded Unit Count

Exact Mass

658.18342g/mol

Formal Charge

Heavy Atom Count

MeSH Entry Terms

tris(2-phenylpyridine)iridium(III)

Monoisotopic Mass

658.18342g/mol

Rotatable Bond Count