CAS 13463-67-7 Titanium(IV) oxide, mixture of rutile and anatase

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Titanium(IV) oxide, mixture of rutile and anatase

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Catalog Number

ACM13463677-3

CAS Number

13463-67-7

Product Name

Titanium(IV) oxide, mixture of rutile and anatase

Structure

Category

Organic Solar Cell (OPV) Materials

Synonyms

Titanium dioxide

Description

Nanopowder , <100 nm particle size (BET), 99.5% trace metals basis

IUPAC Name

dioxotitanium

Molecular Weight

79.87 g/mol

Molecular Formula

TiO2

Canonical SMILES

O=[Ti]=O

InChI

1S/2O.Ti

InChI Key

GWEVSGVZZGPLCZ-UHFFFAOYSA-N

Boiling Point

>200 °C

Melting Point

1825 °C (lit.)

Flash Point

Not applicable

Purity

nanoparticle,<250 nmparticlesizeDLS,paste,53-57 wt.%indiethyleneglycolmonobutylether/ethyleneglycol,99.9%tracemetalsbasis

Density

1.8 g/mL±0.2 at 25 °C

Solubility

less than 1 mg/mL at 68° F (NTP, 1992);Insoluble in water and organic solvents. Dissolves slowly in hydrofluoric acid and in hot concentrated sulphuric acid.;Insoluble in water;Soluble in hot concentrated sulfuric acid; in hydrofluoric acid; insoluble in hydrochloric acid, nitric acid or diluted sulfuric acid;INSOL IN ORG SOLVENTS;SOLUBLE IN ALKALI;Solubility in water: none;Insoluble

Appearance

nanoparticle

Application

TiO2 can be used in a variety of medical implants, such as dental implants, spinal fixations, and joint replacements. It can also be used in a stable colloidal solution for the formation of RPMI cell culture medium. It forms a conductive layer in the fabrication of dye sensitized solar cells.Photoelectrodes of varying properties can be made using colloidal suspensions of titanium(IV) oxide nanoparticles.

Storage

2-8°C

Assay

99.5% trace metals basis

Color/Form

White, tetragonal crystals;White powder in two crystalline forms, anatase and rutile;AMORPHOUS, INFUSIBLE POWDER;White powder

Complexity

18.3

Covalently-Bonded Unit Count

EC Number

236-675-5;215-282-2;215-280-1;236-675-5;619-318-1

Exact Mass

79.93777g/mol

Form

Nanopowder

Formal Charge

Heavy Atom Count

ICSC Number

0338

MDL Number

MFCD00011269

MeSH Entry Terms

anatase;anatase titanium dioxide;brookite;food additive E171;nano-anatase;nano-TiO₂;rutile;Titania;titanium dioxide;titanium oxide;titanium white

Monoisotopic Mass

79.93777g/mol

NSC Number

15204

Odor

Odorless

Other Experimental

GRAVIMETRIC FACTOR: 0.33279;ANATASE: INDEX OF REFRACTION (NA): 2.554; 2.493; SPECIFIC GRAVITY: 3.84; BROOKITE: INDEX OF REFRACTION (NA): 2.583; 2.586; 2.741; SPECIFIC GRAVITY: 4.17 RUTILE: SPECIFIC GRAVITY: 4.26; INDEX OF REFRACTION (NA): 2.616; 2.903;Reactivity depends on previous heat treatment; prolonged heating produces less soluble material; made soluble by fusion with potassium bisulfate or alkali hydroxides or carbonates to form alkali titanates; Index of refraction: 2.7 (Titania crystals);RUTILE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: P4/MNM(136); 2 G FORMULA WT/UNIT CELL; X-RAY CRYSTALLOGRAPHIC DATA: AO= 4.5937 + OR - 0.0005; CO= 2.9618 + OR - 0.0010;ANATASE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: I41/AMD(141); 4 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 3.785 + OR - 0.002; CO= 9.514 + OR - 0.006;BROOKITE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: ORTHORHOMBIC; SPACE GROUP: PCAB (61); 8 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 5.456 + OR - 0.002; BO= 9.182 + OR - 0.005; CO= 5.143 + OR - 0.003;When substantially pure, a massive single crystal (boule) of rutile has properties of precious gem with a very light straw color and with reflectance, refraction and brilliance measuring greater than those of a diamond. ... high opacity and tinting values are claimed for rutile-like pigments.;Titania is ... large ... crystals (translucent water-white or with yellowish cast) these crystals have refractive index ... higher than diamonds ... but lack hardness of diamonds.;Possesses perhaps the greatest hiding power of all inorg white pigments;Brown tetragonal crystals; MP: 1560 °C; density: 3.9 g/cu cm /Titanium(IV)oxide (Anatase)/;White, orthorhombic crystals; density: 4.17 g/cu cm /Titanium(IV)oxide (Brookite)/;White, tetrahedral crystals; MP: 1843 °C; BBP: approximately 3000 °C; density: 4.17 g/cu cm. Insoluble in water, dilute acid; soluble in concentrated acid /Titanium(IV)oxide (Rutile)/

Packaging

25 g/100 g

Refractive Index

n20/D 1.520

Rotatable Bond Count

Specific Surface Area

BET surf. area 50 m2/g±18 (BET surface area of starting nanopowder)

Vapor Pressure

0 mm Hg at 68 °F Essentially (NTP, 1992);0 mmHg (approx);0 mmHg (approx)

MSDS

Download MSDS

COA

Download COA

Spec Sheet

Download Spec Sheet

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13463-67-7
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nanoparticle,<250 nmparticlesizeDLS,paste,53-57 wt.%indiethyleneglycolmonobutylether/ethyleneglycol,99.9%tracemetalsbasis
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