CAS 29681-57-0 T-Butyldimethylsilane - Materials / Alfa Chemistry

NAVIGATION

T-Butyldimethylsilane

PRICE INQUIRY

Catalog Number

ACM29681570

CAS Number

29681-57-0

Product Name

T-Butyldimethylsilane

Structure

Category

Salt

Synonyms

tert-ButyldimethylsilaneButyldimethylsilaneTert-Butyl(Dimethyl)Silyl

IUPAC Name

tert-butyl(dimethyl)silicon

Molecular Weight

116.28 g/mol

Molecular Formula

C6H16Si

Canonical SMILES

CC(C)(C)[Si](C)C

InChI Key

ILMRJRBKQSSXGY-UHFFFAOYSA-N

Boiling Point

82.697 °C(760 mmHg)

Flash Point

-22.778 °C

Purity

0.95

Density

0.701 g/mLat25°C(lit.)

Appearance

Liquid

Application

T-Butyldimethylsilane serves multiple purposes in chemical synthesis and protection processes. It is prominently used for protecting hydroxy groups in sugars, a vital step in carbohydrate chemistry. Additionally, its oxidation product, tert-butyldimethylsilyl hydroperoxide, aids in creating luminescent sources and prostanoids such as clavulons. In catalyst chemistry, T-Butyldimethylsilane reacts with an iridium complex to form an active catalyst for the regioselective silylation of various methyl hexopyranosides and related compounds. Furthermore, when used in silylcarbobicyclization reactions with certain catalysts under carbon monoxide pressure, it yields innovative 2-silylbicyclo[3.3.0]octa-1,5-dien-3-ones, demonstrating its versatile role in advancing synthetic methodologies.

Exact Mass

116.10200

Hazard Statements

F,Xi

Packaging

10 g; 100 g;

Safety Description

S16-S26-S36

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