CAS 9002-98-6 Polyethyleneimine (ca. 30% in Water)

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Polyethyleneimine (ca. 30% in Water)

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Catalog Number

ACM9002986-16

Product Name

Polyethyleneimine (ca. 30% in Water)

Structure

CAS

9002-98-6

Category

Polymers

Description

Ethyleneimine, stabilized appears as a clear colorless liquid with an ammonia-like odor. Flash point 12°F. Less dense than water. Flammable over a wide range of vapor-air concentrations. Vapors irritate the skin, eyes, nose, and throat. May be toxic by prolonged inhalation, skin absorption, or ingestion. Carcinogenic. Vapors heavier than air. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently.;COLOURLESS LIQUID WITH PUNGENT ODOUR.;Colorless liquid with an ammonia-like odor.;Colorless liquid with an ammonia-like odor. [Note: Usually contains inhibitors to prevent polymerization.]

IUPAC Name

aziridine

Molecular Weight

43.07g/mol

Molecular Formula

C2H5N;CH2NHCH2;C2H5N

Canonical SMILES

C1CN1

InChI

InChI=1S/C2H5N/c1-2-3-1/h3H,1-2H2

InChI Key

NOWKCMXCCJGMRR-UHFFFAOYSA-N

Boiling Point

131 to 133 °F at 760 mm Hg (EPA, 1998);56.0 °C;55-56 °C at 760 mm Hg;56-57 °C;133°F;133°F

Melting Point

-98 °F Freezing Point (EPA, 1998);-77.9 °C;Freezing point: -71.5 °C;-74 °C;-97°F;-97°F

Flash Point

12 °F (EPA, 1998);12 °F (-11 °C) (Closed cup);-11 °C c.c.;12°F;12°F

Density

0.8321 at 68 °F (EPA, 1998);0.8321 at 24 °C/4 °C;Relative density (water = 1): 0.8;0.83;0.83

Solubility

Miscible (NIOSH, 2016);23.22 M;SOL IN ALKALI;Soluble in ethanol; slightly soluble in ether; very soluble in chloroform; miscible in organic solvents;In water, 1X10+6 mg/L (miscible);Solubility in water: miscible;Miscible

Color/Form

Oily, water-white liquid;Colorless liquid ... [Note: Usually contains inhibitors to prevent polymerization].

Complexity

10.3

Corrosivity

Corrosive

Covalently-Bonded Unit Count

EC Number

205-793-9;618-346-1

Exact Mass

43.042199g/mol

Formal Charge

Heat of Vaporization

333 Btu/lb= 185 cal/g= 7.75 x 10+5 J/kg

Heavy Atom Count

ICSC Number

0100

Log P

log Kow = -0.28 (est);-0.36

MeSH Entry Terms

aziridine;aziridine, conjugate acid;ethyleneimine;ethylenimine

Monoisotopic Mass

43.042199g/mol

NSC Number

196335;134422;124036;124035;124034

Odor

Pungent, ammonia-like odor;Amine odor

Other Experimental

1 mg/cu m = 0.56 ppm; 1 ppm = 1.79 mg/cu m;Saturation concentration = 567 g/cu m at 30 °C.;Heat of solution: -26 Btu/lb= -14 cal/g= -0.6x10+5 J/kg (est);Heat of polymerization: (est) -900 Btu/lb= -500 cal/g= -20x10+5 J/kg;... tend/s/ to polymerize with explosive violence in the presence of acids and acid-forming and oxidizing materials;Henry's Law constant = 1.21X10-5 atm-cu m/mol at 25 °C (est);Hydroxyl radical reaction rate constant = 6.10X10-12 cu-cm/molec-sec at 25 °C

Refractive Index

Index of refraction = 1.412 at 25 C/D

Rotatable Bond Count

RTECS Number

KX5075000

UNII

54P5FEX9FH

UN Number

1185;1185;1185;1185;1185

Vapor Density

1.48 (EPA, 1998) (Relative to Air);1.48 (Air=1);Relative vapor density (air = 1): 1.5;1.48

Vapor Pressure