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  • Poly(4-methyl-1-pentene)

    Catalog Number
    ACM25068262-1
    CAS Number
    25068-26-2
    Product Name
    Poly(4-methyl-1-pentene)
    Category
    Hydrophobic Polymers; Polymers
    Description
    4-methyl-1-pentene is a colorless liquid. (USCG, 1999)
    IUPAC Name
    4-methylpent-1-ene
    Molecular Weight
    84.16g/mol
    Molecular Formula
    C6H12
    Canonical SMILES
    CC(C)CC=C
    InChI
    InChI=1S/C6H12/c1-4-5-6(2)3/h4,6H,1,5H2,2-3H3
    InChI Key
    WSSSPWUEQFSQQG-UHFFFAOYSA-N
    Boiling Point
    127.4 to 129.2 °F at 760 mm Hg (USCG, 1999);53.9 °C
    Melting Point
    -153.6 °C
    Flash Point
    -25 °F (USCG, 1999)
    Density
    0.665 (USCG, 1999)
    Solubility
    5.70e-04 M
    Application
    Poly(4-Methyl-1-Pentene) serves as a versatile material well-suited for a variety of demanding applications due to its unique properties. Introduced initially by Imperial Chemical Industries and later exclusively produced by Mitsui Petrochemical Industries, this polymer is created using a Ziegler-Natta catalyst in a controlled environment. Its composition, enhanced with a comonomer like 1-hexene, yields a predominantly isotactic structure that offers significant advantages over other polyolefins. Notably, it possesses the lowest specific gravity among current polymers at 0.83, along with impressive thermal properties, such as a crystalline melting point of 240°C and a Vicat softening temperature of 179°C, ensuring stability up to around 200°C. Its transparency rivals that of poly(methyl methacrylate) and polystyrene. Additionally, Poly(4-Methyl-1-Pentene) demonstrates exceptional resistance to various chemical environments akin to polypropylene, although it is susceptible to environmental stress cracking similar to low-density polyethylene. Despite its higher permeability to gases and water vapor relative to other polyolefins, it remains easily processable via standard extrusion and injection molding techniques. These attributes make it an ideal choice for applications requiring transparency and heat resistance, such as medical and laboratory ware, coating for microwaveable and oven-safe food containers, and films for decorative laminates and printed circuit boards.
    Complexity
    35.3
    Covalently-Bonded Unit Count
    1
    EC Number
    211-720-1
    Exact Mass
    84.0939g/mol
    Formal Charge
    0
    Heavy Atom Count
    6
    MeSH Entry Terms
    poly(4-methyl-1-pentene)
    Monoisotopic Mass
    84.0939g/mol
    NSC Number
    15091
    Rotatable Bond Count
    2
    UNII
    X10HRJ2Y7W
    UN Number
    1993
    Vapor Pressure
    438.93 mm Hg (USCG, 1999);271.64 mmHg
    XLogP3
    2.7
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