Category
3D Printing Materials; Phosphors - Phosphor Materials
Synonyms
parisred;Lead oxide,red,Lead(II,IV) oxide;Pb3-O4;MINIUM;RED LEAD
Description
Lead(II,IV) oxide, also called minium, red lead or triplumbic tetroxide, is a bright red or orange crystalline or amorphous pigment. Chemically, red lead is Pb3O4, or 2 PbO·PbO2. Pb3O4,is [2PbO].[PbO2] or Lead(II,IV) oxide. It is used in the manufacture of batteries, lead glass and rust-proof primer paints.
IUPAC Name
1,3,5,7-tetraoxa-2ж╦2,4,6ж╦2-triplumbaspiro[3.3]heptane
Canonical SMILES
O1[Pb]O[Pb]12O[Pb]O2
InChI Key
XMFOQHDPRMAJNU-UHFFFAOYSA-N
Boiling Point
Decomposes between 500 and 530 °C
Solubility
Insoluble in water;Insoluble in alcohol; soluble in excess glacial acetic acid, in hot hydrochloric acid with evolution of chlorine, in dilute nitric acid in presence of hydrogen peroxide;Partly soluble in acids;Solubility in water: none
Application
Lead oxide serves as a versatile compound utilized across a wide range of applications due to its diverse chemical and physical properties. Known for its red to orange powder form, lead oxide is an essential component in the creation of plasters and ointments and plays a crucial role in the manufacture of colorless glass and protective paints for iron and steel. It is also used as a glaze for faience and as a flux for porcelain painting. Beyond these uses, lead oxide contributes to the production of oil colors for ship paints and varnishes, the coloring of rubber, and the cementation of glass and gas or steam pipes. In the realm of electronics, lead oxide is a key ingredient in storage batteries and is used to create pencils for writing on glass, as well as in the production of lead peroxide and matches. Its application extends further as a catalyst in specific reactions due to its varied oxidation states and forms, which range from lead monoxide to red lead and others. This versatility has ensured its widespread use since ancient times, notably among the Romans, and remains significant in modern materials science and manufacturing.
Color/Form
Bright-red, heavy powder
Covalently-Bonded Unit Count
1
MeSH Entry Terms
azarcon;lead tetraoxide;lead tetroxide;red lead oxide
Monoisotopic Mass
687.90961g/mol
Other Experimental
Decomposes at approximately 500 °C with evolution of oxygen;Density reported variously 8.32 to 9.16;Heat capacity: 155 J/mol-K at 27 °C
Stability
Stable. May react vigorously with reducing agents.
Vapor Pressure
10 mm Hg ( 0 °C)