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Lead oxide

Catalog Number
ACM1314416
CAS Number
1314-41-6
Product Name
Lead oxide
Structure
Category
3D Printing Materials; Phosphors - Phosphor Materials
Synonyms
parisred;Lead oxide,red,Lead(II,IV) oxide;Pb3-O4;MINIUM;RED LEAD
Description
Lead(II,IV) oxide, also called minium, red lead or triplumbic tetroxide, is a bright red or orange crystalline or amorphous pigment. Chemically, red lead is Pb3O4, or 2 PbO·PbO2. Pb3O4,is [2PbO].[PbO2] or Lead(II,IV) oxide. It is used in the manufacture of batteries, lead glass and rust-proof primer paints.
IUPAC Name
1,3,5,7-tetraoxa-2ж╦2,4,6ж╦2-triplumbaspiro[3.3]heptane
Molecular Weight
686g/mol
Molecular Formula
O4Pb3
Canonical SMILES
O1[Pb]O[Pb]12O[Pb]O2
InChI
InChI=1S/4O.3Pb
InChI Key
XMFOQHDPRMAJNU-UHFFFAOYSA-N
Boiling Point
Decomposes between 500 and 530 °C
Melting Point
500ºC
Density
9.1
Solubility
Insoluble in water;Insoluble in alcohol; soluble in excess glacial acetic acid, in hot hydrochloric acid with evolution of chlorine, in dilute nitric acid in presence of hydrogen peroxide;Partly soluble in acids;Solubility in water: none
Appearance
Red powder
Application
Lead oxide serves as a versatile compound utilized across a wide range of applications due to its diverse chemical and physical properties. Known for its red to orange powder form, lead oxide is an essential component in the creation of plasters and ointments and plays a crucial role in the manufacture of colorless glass and protective paints for iron and steel. It is also used as a glaze for faience and as a flux for porcelain painting. Beyond these uses, lead oxide contributes to the production of oil colors for ship paints and varnishes, the coloring of rubber, and the cementation of glass and gas or steam pipes. In the realm of electronics, lead oxide is a key ingredient in storage batteries and is used to create pencils for writing on glass, as well as in the production of lead peroxide and matches. Its application extends further as a catalyst in specific reactions due to its varied oxidation states and forms, which range from lead monoxide to red lead and others. This versatility has ensured its widespread use since ancient times, notably among the Romans, and remains significant in modern materials science and manufacturing.
Color/Form
Bright-red, heavy powder
Complexity
67.4
Covalently-Bonded Unit Count
1
EC Number
215-235-6
Exact Mass
685.90743g/mol
Formal Charge
0
Heavy Atom Count
7
ICSC Number
1002
Log P
-1.41600
MDL Number
MFCD00078491
MeSH Entry Terms
azarcon;lead tetraoxide;lead tetroxide;red lead oxide
Monoisotopic Mass
687.90961g/mol
Other Experimental
Decomposes at approximately 500 °C with evolution of oxygen;Density reported variously 8.32 to 9.16;Heat capacity: 155 J/mol-K at 27 °C
Rotatable Bond Count
0
RTECS Number
OG5425000
Stability
Stable. May react vigorously with reducing agents.
UN Number
3077
Vapor Pressure
10 mm Hg ( 0 °C)
WGK Germany
3
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