CAS 775-12-2 Diphenylsilane - Materials / Alfa Chemistry

NAVIGATION

Diphenylsilane

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Catalog Number

ACM775122

CAS Number

775-12-2

Product Name

Diphenylsilane

Structure

Category

Salt

Synonyms

Diphenylsilane, Silane, diphenyl-, 148482_ALDRICH, NSC33013, EINECS 212-271-4, NSC 33013, NSC168693, 775-12-2, 17950-94-6

IUPAC Name

di(phenyl)silicon

Molecular Weight

184.31 g/mol

Molecular Formula

C12H12Si

InChI Key

BPYFPNZHLXDIGA-UHFFFAOYSA-N

Boiling Point

97 °C(12 mmHg)

Melting Point

79 °C

Flash Point

98 °C

Purity

0.97

Density

0.993 g/mL

Appearance

Colorless to Light yellow clear liquid

Application

Diphenylsilane serves a crucial role as a versatile reagent in various chemical transformations. It is primarily used for the deoxygenation of secondary and primary alcohols through a radical chain process, donating hydrogen atoms with the initiation of triethylborane-air. This clear, colorless liquid efficiently deaminates isonitriles and dehalogenates bromo- and iodo-compounds using radical chain chemistry. Diphenylsilane is also a key component in the preparation of fluorescent film sensors for detecting vapor-phase nitroaromatic explosives by assembling monolayers on glass surfaces. Its applications extend to the reduction of carboxylic acid derivatives, converting esters to alcohols with high yields when catalyzed by rhodium complexes. Additionally, diphenylsilane facilitates sequential C-Si bond formations, which are pivotal in developing silanediol peptide isostere precursors, and is used in various reductions, including ionic reductions of enones, reductive cyclization of unsaturated ketones, and the conversion of thio esters to ethers. It plays a role in asymmetric reductions of methyl ketones and other ketones, and aids in the reductive cleavage of allyl acetates, demonstrating its flexibility and efficacy in synthetic organic chemistry.

Storage

Store under inert gas

EC Number

212-271-4

Exact Mass

184.07100

Hazard Statements

H315 : Causes skin irritation.
H319 : Causes serious eye irritation.

MDL Number

MFCD00003002

Packaging

10 g; 100 g;

Precautionary Statements

P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation °Ccurs: Get medical advice/ attention.

Properties

Liquid

Safety Description

37/39-26

Signal Word

Warning

Specific Gravity

Stability

Stable at room temperature in closed containers under normal storage and handling conditions.

WGK Germany

MSDS

Download MSDS