CAS 12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

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Catalog Number

ACM12092476-2

Product Name

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Structure

CAS

12092-47-6

Category

Salt

Synonyms

Bis(cycloocta-1,5-diene)dichlorodirhodium

IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride;

Molecular Weight

493.08

Molecular Formula

C16H24Cl2Rh2

Canonical SMILES

C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh]

InChI

InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;2*1H;/p-2/b2*2-1-,8-7-;

InChI Key

PDJQCHVMABBNQW-MIXQCLKLSA-L

Melting Point

243 °C

Purity

98%

Appearance

Orange yellow powder

Application

Catalyst for coupling 1,3-dienes with activate methylene compounds.

Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.

Rhodium source for asymmetric reductive aldol reaction.

Cis-hydroboration of terminal alkynes.

Rhodium source for [5 + 2] additions.

Highly enantioselective for [2+2+2] carbocyclization reactions.

Enantioselective hydroboration of cyclopropenes.

Storage

2-8°C

Complexity

72.6

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Defined Bond Stereocenter Count

EC Number

235-157-6

Exact Mass

491.93649

Formal Charge