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Boric acid, 99.99% metals basis

Catalog Number
ACM10043353-1
CAS Number
10043-35-3
Product Name
Boric acid, 99.99% metals basis
Structure
Category
Electronic Chemicals
Description
Boric acid is an odorless white solid. Melting point 171°C. Sinks and mixes with water. (USCG, 1999);DryPowder; Liquid; OtherSolid; OtherSolid, Liquid; PelletsLargeCrystals;PelletsLargeCrystals;Colourless, odourless, transparent crystals or white granules or powder; slightly unctuous to the touch; occurs in nature as the mineral sassolite;Solid;ODOURLESS COLOURLESS CRYSTALS OR WHITE POWDER.;Odorless white solid.
IUPAC Name
boric acid
Molecular Weight
61.84g/mol
Molecular Formula
H3BO3;BH3O3;B(OH)3;H3BO3;B(OH)3;BH3O3
Canonical SMILES
B(O)(O)O
InChI
InChI=1S/BH3O3/c2-1(3)4/h2-4H
InChI Key
KGBXLFKZBHKPEV-UHFFFAOYSA-N
Boiling Point
572 °F at 760 mm Hg (decomposes) (NTP, 1992);572°F
Melting Point
340 °F (NTP, 1992);170.9 °C;171°C;340°F
Density
1.435 at 68 °F (USCG, 1999);1.5 g/cu cm;Relative density (water = 1): 1.5;1.435
Solubility
10 to 50 mg/mL at 66° F (NTP, 1992);Soluble in hot water, partially soluble in cold water;Solubility: in glycerol 17.5% at 25 °C; ethylene glycol 18.5% at 25 °C; in methanol 173.9 g/L at 25 °C; in ethanol 94.4 g/L at 25 °C; in acetone 0.6% at 25 °C; ethyl acetate 1.5% at 25 °C;Water solubility: 2.52% at 0 °C; 3.49% at 10 °C; 4.72% at 20 °C; 6.23% at 30 °C; 8.08% at 40 °C; 10.27% at 50 °C; 12.97% at 60 °C; 15.75% at 70 °C; 19.10% at 80 °C; 23.27% at 90 °C; 27.53% at 100 °C;Solubility in water is increased by hydrochloric acid;In water, 5.0X10+4 mg/L at 25 °C;50 mg/mL at 25 °C;Solubility in water, g/100ml at 20 °C: 5.6
Application
Boric acid, 99.99% metals basis, serves a diverse range of applications primarily due to its excellent properties and high purity. This compound, which can manifest as a white crystalline powder or colorless crystals, is instrumental in the field of molecular biology, particularly in the purification of DNA and RNA and as a component of biological buffers. It plays a critical role in studying the toxic impacts of boron on plant growth and antioxidant systems and examining the effects of boric acid in biological models, such as the uptake in different regions of a rat's brain. With its antimicrobial preservative qualities, boric acid finds use in a variety of products, including eye drops, cosmetics, ointments, and topical creams. It also contributes to pH control owing to its buffering capacity and has been employed in external preparations for its antiseptic properties. Its applications extend to therapeutic uses, like the treatment of yeast infections with suppositories, although it is now largely replaced by more advanced disinfectants in certain uses due to the availability of less toxic alternatives.
Color/Form
Colorless, transparent crystals or white granules or powder;Colorless triclinic crystals;White waxy triclinic solid plates
Complexity
8
Covalently-Bonded Unit Count
1
EC Number
233-139-2;233-139-2;234-343-4
Exact Mass
62.017524g/mol
Formal Charge
0
Heavy Atom Count
4
ICSC Number
0991
Log P
log Kow = 0.175;0.18;-1.09
MeSH Entry Terms
boric acid;boron oxide hydroxide;orthoboric acid
Monoisotopic Mass
62.017524g/mol
NSC Number
81726
Odor
Odorless
Other Experimental
Slightly unctuous to touch; volatile with steam; solubility in water increased by hydrochloric, citric or tartaric acids;Loses 1.5H₂O at 300 °C;Standard enthalpy of formation: -1094.3 kJ/mol (crystal); -994.1 kJ/mol (gas);pH at 20 °C: 6.1 (0.1% solution); 5.1 (1.0% solution); 3.7 (4.5% solution);Boric acid will form soluble salts with monovalent cations (e.g. Na2B407.1OH20, 6% in water) and insoluble salts with divalent cations (e.g. CaB407.6H20, almost insoluble in cold water).;Henry's Law constant = 2.6X10-12 atm-cum/mole at 25 °C, based on measured water solubility and vapor pressure;Hydroxyl radical reaction rate constant = 4.2X10-13 cu cm/molecule-sec at 25 °C (est)
Refractive Index
Index of refraction: 1.337, 1.461, 1.462
Rotatable Bond Count
0
RTECS Number
ED4550000
Stability
Stable in air.;...Stable up to 100 °C
UNII
R57ZHV85D4
Vapor Pressure
1.6X10-6 mm Hg at 25 °C (2.136X10-4 Pa); log P (in Pa) = 26.83 - 9094/T where T is deg K;Vapor pressure at 20 °C: negligible
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