CAS 14694-95-2 Tris(triphenylphosphine)rhodium(I) chloride

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Salt

Tris(triphenylphosphine)rhodium(I) chloride

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Catalog Number

ACM14694952-1

Product Name

Tris(triphenylphosphine)rhodium(I) chloride

Structure

CAS

14694-95-2

Category

Salt

Synonyms

Chlorotris-(triphenylphosphino)-rhodium

IUPAC Name

rhodium;triphenylphosphane;chloride;

Molecular Weight

925.21

Molecular Formula

C54H45ClP3Rh

Canonical SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]

InChI

InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h3*1-15H;1H;/p-1

InChI Key

QBERHIJABFXGRZ-UHFFFAOYSA-M

Melting Point

245-250 °C

Purity

98%

Appearance

Magenta crystal

Application

A homogeneous hydrogenation catalyst which operates under mild conditions.

Catalyst for the decarbonylation of aldehydes.

Catalyst for regio- and stereoselective allylic substitution reactions.

Alkyne hydro-phosphorylation

Heck-type reaction with α,β-unsaturated esters.

Alkyne arylation

Allylic alcohol-olefin coupling.

Terminal alkenes from ketones.

Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones.

Reductive deprotection of silyl groups.

Storage

2-8°C

Complexity

202

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

EC Number

238-744-5

Exact Mass

924.14776

Formal Charge

-1