CAS 52522-40-4 Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

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Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

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Catalog Number

ACM52522404

Product Name

Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

Structure

CAS

52522-40-4

Category

Salt

Synonyms

Tris(dibenylideneacetone)dipalladium-chloroform; tris-(dibenzylideneacetone)-dipalladium(o)-chloroform adduct; tris(dibenzylideneacetone)-dipalladium (0) chloroform adduct; DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT; tris(dibenzylideneacetone) dipalladium(0)chloroform adduct; GC10022; I14-10041; tris(dibenzylideneacetone) dipalladium chloroform; tris(dibenzylideneacetone)dipalladium (0)chloroform adduct; S-3159;

IUPAC Name

chloroform;(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium;

Molecular Weight

1035.103g/mol

Molecular Formula

C52H43Cl3O3Pd2;

Canonical SMILES

C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C(Cl)(Cl)Cl.[Pd].[Pd];

InChI

InChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;/b3*13-11+,14-12+;;;;

InChI Key

LNAMMBFJMYMQTO-FNEBRGMMSA-N;

Application

Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.

Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).

Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2'biphenylylene ditriflates.

Paladium catalyst for regioand enantioselective allylic alkylation of ketones through allyl enol carbonates.

Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.

Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.

Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.

Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.

Palladium catalyst for asymmetric addition of oxindoles and allenes.

Catalyst for diastereoand enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.

Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.

Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.

Storage

0-6°C

Complexity

280

Covalently-Bonded Unit Count

Defined Bond Stereocenter Count

EC Number

610-856-2

Exact Mass

1034.035g/mol

Heavy Atom Count

Monoisotopic Mass