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  • Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

  • Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

    Catalog Number
    ACM52522404
    CAS Number
    52522-40-4
    Product Name
    Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct
    Structure
    Category
    Salt
    Synonyms
    Tris(dibenylideneacetone)dipalladium-chloroform; tris-(dibenzylideneacetone)-dipalladium(o)-chloroform adduct; tris(dibenzylideneacetone)-dipalladium (0) chloroform adduct; DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT; tris(dibenzylideneacetone) dipalladium(0)chloroform adduct; GC10022; I14-10041; tris(dibenzylideneacetone) dipalladium chloroform; tris(dibenzylideneacetone)dipalladium (0)chloroform adduct; S-3159;
    IUPAC Name
    chloroform;(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium;
    Molecular Weight
    1035.103g/mol
    Molecular Formula
    C52H43Cl3O3Pd2;
    Canonical SMILES
    C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C(Cl)(Cl)Cl.[Pd].[Pd];
    InChI
    InChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;/b3*13-11+,14-12+;;;;
    InChI Key
    LNAMMBFJMYMQTO-FNEBRGMMSA-N;
    Application
    Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.

    Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).

    Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2'biphenylylene ditriflates.

    Paladium catalyst for regioand enantioselective allylic alkylation of ketones through allyl enol carbonates.

    Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.

    Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.

    Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.

    Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.

    Palladium catalyst for asymmetric addition of oxindoles and allenes.

    Catalyst for diastereoand enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.

    Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.

    Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.
    Storage
    0-6°C
    Complexity
    280
    Covalently-Bonded Unit Count
    6
    Defined Bond Stereocenter Count
    6
    EC Number
    610-856-2
    Exact Mass
    1034.035g/mol
    Heavy Atom Count
    60
    Monoisotopic Mass
    1032.035g/mol
    Rotatable Bond Count
    12
    Topological Polar Surface Area
    51.2A^2
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