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Triruthenium dodecacarbonyl

Catalog Number
ACM15243331
Product Name
Triruthenium dodecacarbonyl
Structure
CAS
15243-33-1
Category
Vapor Deposition Precursors
Synonyms
Ruthenium carbonyl,
tri-Ruthenium dodecacarbonyl
Description
Atomic number of base material: 44 Ruthenium
Molecular Weight
639.33
Molecular Formula
Ru3(CO)12
Canonical SMILES
[Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/12CO.3Ru/c12*1-2;;;,NQZFAUXPNWSLBI-UHFFFAOYSA-N
InChI Key
NQZFAUXPNWSLBI-UHFFFAOYSA-N
Purity
Ru ≥25.7%
Appearance
orange crystals
Application
Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.[5]
Storage
room temp
EC Number
239-287-4
Hazard Statements
H332
MDL Number
MFCD00011209
Packaging
1, 5, 50 g in glass bottle
Safety Description
Warning
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