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Trigonox 101

Catalog Number
ACMA00016402
Product Name
Trigonox 101
Category
Polymerization Initiators; Polymers
Description
2,5-dimethyl-2,5-di-(tert-butylperoxy)hexane is a clear, yellow liquid. (NTP, 1992)also for storage and transport mixed with inert solid.;Liquid; OtherSolid
IUPAC Name
2,5-bis(tert-butylperoxy)-2,5-dimethylhexane
Molecular Weight
290.44g/mol
Molecular Formula
C16H34O4
Canonical SMILES
CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C
InChI
InChI=1S/C16H34O4/c1-13(2,3)17-19-15(7,8)11-12-16(9,10)20-18-14(4,5)6/h11-12H2,1-10H3
InChI Key
DMWVYCCGCQPJEA-UHFFFAOYSA-N
Boiling Point
122 to 126 °F at 0.1 mm Hg (NTP, 1992)
Melting Point
46 °F (NTP, 1992);8.0 °C
Flash Point
185 °F (NTP, 1992)
Solubility
less than 1 mg/mL at 73° F (NTP, 1992)
Application
Trigonox 101 is a versatile, colorless to light yellow liquid designed primarily for initiating degradation in polypropylene and serving as a monomer scavenger in styrene polymerization. This efficient peroxide operates effectively within a temperature range of 200-250°C, making it optimal for the controlled breakdown of polypropylene. Additionally, Trigonox 101 acts as a chaser catalyst, significantly reducing residual monomers during the mass polymerization of styrene. It is also utilized in the crosslinking process for both natural and synthetic rubber, as well as thermoplastic polyolefins, providing compounds with excellent scorch safety. When used in rubber formulations, it ensures safe processing at a temperature of 135°C, maintaining a rheometer ts2 greater than 20 minutes, and facilitates typical crosslinking at 175°C with a rheometer t90 of approximately 12 minutes.
Complexity
252
Covalently-Bonded Unit Count
1
EC Number
201-128-1
Exact Mass
290.24571g/mol
Formal Charge
0
Heavy Atom Count
20
Monoisotopic Mass
290.24571g/mol
NSC Number
38203
Rotatable Bond Count
9
UNII
923755EYY5
UN Number
3108
XLogP3
3.9
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