CAS 75-94-5 Trichlorovinylsilane - Materials / Alfa Chemistry

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Trichlorovinylsilane

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Catalog Number

ACM75945

CAS Number

75-94-5

Product Name

Trichlorovinylsilane

Structure

Category

Self-Assembly Materials; Silane Coupling Agents; Self Assembly and Lithography; POSS Nanohybrid Materials; Self Assembly and Contact Printing Materials

Description

Vinyltrichlorosilane appears as a colorless to pale yellow fuming liquid with a pungent odor. Vapor and liquid may cause burns. More dense than water. Vapors are heavier than air.;Liquid

IUPAC Name

trichloro(ethenyl)silane

Molecular Weight

161.48g/mol

Molecular Formula

C2H3Cl3Si

Canonical SMILES

C=C[Si](Cl)(Cl)Cl

InChI

InChI=1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2

InChI Key

GQIUQDDJKHLHTB-UHFFFAOYSA-N

Boiling Point

195.1 °F at 760 mm Hg (USCG, 1999);91.5 °C;91.5 °C

Melting Point

-139 °F (USCG, 1999);-95.0 °C;-95 °C

Flash Point

70 °F (NFPA, 2010);70 °F (21 °C) (open cup)

Density

1.26 at 68 °F (USCG, 1999);1.2426 g/cu cm at 20 °C

Solubility

Soluble in most organic solvents;Very soluble in chloroform

Application

Trichlorovinylsilane is a versatile chemical known for its ability to act as a crucial intermediate in the production of silicones and as a coupling agent in adhesives and bonds. This colorless or pale-yellow liquid is notable for its reactivity, readily hydrolyzing with the release of hydrogen chloride and polymerizing easily. It is soluble in most organic solvents and reacts with alcohols, which expands its utility across various applications. One notable use of trichlorovinylsilane is in biomedical research, where it has been explored for treating materials like Pluronic F127 and chitosan, enhancing the attachment and proliferation of endothelial cells on biomaterials. Additionally, it serves as a precursor in the preparation of epoxy-terminated carbosiloxane, illustrating its broad applicability in advanced material science.

Color/Form

Fuming liquid;Liquid;Colorless or pale yellow liquid

Complexity

54.3

Corrosivity

Corrosive

Covalently-Bonded Unit Count

EC Number

200-917-8

Exact Mass

159.90696g/mol

Formal Charge

Heat of Vaporization

88 Btu/lb = 49 cal/g = 2.0X10+5 J/kg

Heavy Atom Count

MeSH Entry Terms

trichlorovinylsilane

Monoisotopic Mass

159.90696g/mol

NSC Number

93872

Odor

Sharp, choking; like hydrochloric acid

Other Experimental

Reacts violently with water, moist air, or steam to produce toxic and corrosive fumes;Reacts with alcohol;Readily hydrolyzed, with liberation of hydrogen chloride; polymerizes easily;The reaction of organosilanes with halogens and halogen cmpd usually proceeds in good yield through cleavage of the Si--H bond and formation of the silicon-halogen bond. Reaction with fluorine, however, does not proceed satisfactorily because of cleavage of not only the Si--H but also C--Si and C--H bonds. Direct halogenation with chlorination, bromine, and iodine proceeds smoothly, however. /Organosilanes/

Refractive Index

Index of refraction = 1.4295 at 20 °C/D

Rotatable Bond Count

UNII

Q423F9NPBA

UN Number

1305;1305;1305

Vapor Density

5.61 (Air = 1)

Vapor Pressure

65.86 mmHg;65.9 mm Hg at 25 °C

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