Product Name
Trichlorovinylsilane
Category
Self-Assembly Materials; Silane Coupling Agents; Self Assembly and Lithography; POSS Nanohybrid Materials; Self Assembly and Contact Printing Materials
Description
Vinyltrichlorosilane appears as a colorless to pale yellow fuming liquid with a pungent odor. Vapor and liquid may cause burns. More dense than water. Vapors are heavier than air.;Liquid
IUPAC Name
trichloro(ethenyl)silane
Molecular Weight
161.48g/mol
Molecular Formula
C2H3Cl3Si
Canonical SMILES
C=C[Si](Cl)(Cl)Cl
InChI
InChI=1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2
InChI Key
GQIUQDDJKHLHTB-UHFFFAOYSA-N
Boiling Point
195.1 °F at 760 mm Hg (USCG, 1999);91.5 °C;91.5 °C
Melting Point
-139 °F (USCG, 1999);-95.0 °C;-95 °C
Flash Point
70 °F (NFPA, 2010);70 °F (21 °C) (open cup)
Density
1.26 at 68 °F (USCG, 1999);1.2426 g/cu cm at 20 °C
Solubility
Soluble in most organic solvents;Very soluble in chloroform
Color/Form
Fuming liquid;Liquid;Colorless or pale yellow liquid
Covalently-Bonded Unit Count
1
Heat of Vaporization
88 Btu/lb = 49 cal/g = 2.0X10+5 J/kg
MeSH Entry Terms
trichlorovinylsilane
Monoisotopic Mass
159.90696g/mol
Odor
Sharp, choking; like hydrochloric acid
Other Experimental
Reacts violently with water, moist air, or steam to produce toxic and corrosive fumes;Reacts with alcohol;Readily hydrolyzed, with liberation of hydrogen chloride; polymerizes easily;The reaction of organosilanes with halogens and halogen cmpd usually proceeds in good yield through cleavage of the Si--H bond and formation of the silicon-halogen bond. Reaction with fluorine, however, does not proceed satisfactorily because of cleavage of not only the Si--H but also C--Si and C--H bonds. Direct halogenation with chlorination, bromine, and iodine proceeds smoothly, however. /Organosilanes/
Refractive Index
Index of refraction = 1.4295 at 20 °C/D
Vapor Density
5.61 (Air = 1)
Vapor Pressure
65.86 mmHg;65.9 mm Hg at 25 °C