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Titanium(IV) oxide, anatase

Catalog Number
ACM1317700-4
CAS Number
1317-70-0
Product Name
Titanium(IV) oxide, anatase
Structure
Category
3D Printing Materials; Perovskite Materials; Phosphors - Phosphor Materials; Nanoparticles; Organic Solar Cell (OPV) Materials
Synonyms
Titanium dioxide
Description
Nanopowder , <25 nm particle size, 99.7% trace metals basis
IUPAC Name
dioxotitanium
Molecular Weight
79.87 g/mol
Molecular Formula
TiO2
Canonical SMILES
O=[Ti]=O
InChI
1S/2O.Ti
InChI Key
GWEVSGVZZGPLCZ-UHFFFAOYSA-N
Boiling Point
3287 °C (lit.)
Melting Point
1825 °C (lit.)
Flash Point
Not applicable
Purity
nanopowder,<25 nmparticlesize,99.7%tracemetalsbasis
Density
3.9 g/mL at 25 °C (lit.)
Solubility
less than 1 mg/mL at 68° F (NTP, 1992);Insoluble in water and organic solvents. Dissolves slowly in hydrofluoric acid and in hot concentrated sulphuric acid.;Insoluble in water;Soluble in hot concentrated sulfuric acid; in hydrofluoric acid; insoluble in hydrochloric acid, nitric acid or diluted sulfuric acid;INSOL IN ORG SOLVENTS;SOLUBLE IN ALKALI;Solubility in water: none;Insoluble
Appearance
nanopowder
Application
Titania paste may be used as a transparent coating for self cleaning glass.Low optical scattering titania-acrylate nanocomposites have been reported. Metal contacts in solar cells based on titanium dioxide and di-(isothiocyanate)-bis-(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) have been studied.
Storage
2-8°C
Assay
99.7% trace metals basis
Color/Form
White, tetragonal crystals;White powder in two crystalline forms, anatase and rutile;AMORPHOUS, INFUSIBLE POWDER;White powder
Complexity
18.3
Covalently-Bonded Unit Count
1
EC Number
215-280-1
Exact Mass
79.93777g/mol
Form
Nanopowder
Formal Charge
0
Heavy Atom Count
3
ICSC Number
0338
MDL Number
MFCD00011269
MeSH Entry Terms
anatase;anatase titanium dioxide;brookite;food additive E171;nano-anatase;nano-TiO₂;rutile;Titania;titanium dioxide;titanium oxide;titanium white
Monoisotopic Mass
79.93777g/mol
NSC Number
15204
Odor
Odorless
Other Experimental
GRAVIMETRIC FACTOR: 0.33279;ANATASE: INDEX OF REFRACTION (NA): 2.554; 2.493; SPECIFIC GRAVITY: 3.84; BROOKITE: INDEX OF REFRACTION (NA): 2.583; 2.586; 2.741; SPECIFIC GRAVITY: 4.17 RUTILE: SPECIFIC GRAVITY: 4.26; INDEX OF REFRACTION (NA): 2.616; 2.903;Reactivity depends on previous heat treatment; prolonged heating produces less soluble material; made soluble by fusion with potassium bisulfate or alkali hydroxides or carbonates to form alkali titanates; Index of refraction: 2.7 (Titania crystals);RUTILE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: P4/MNM(136); 2 G FORMULA WT/UNIT CELL; X-RAY CRYSTALLOGRAPHIC DATA: AO= 4.5937 + OR - 0.0005; CO= 2.9618 + OR - 0.0010;ANATASE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: I41/AMD(141); 4 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 3.785 + OR - 0.002; CO= 9.514 + OR - 0.006;BROOKITE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: ORTHORHOMBIC; SPACE GROUP: PCAB (61); 8 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 5.456 + OR - 0.002; BO= 9.182 + OR - 0.005; CO= 5.143 + OR - 0.003;When substantially pure, a massive single crystal (boule) of rutile has properties of precious gem with a very light straw color and with reflectance, refraction and brilliance measuring greater than those of a diamond. ... high opacity and tinting values are claimed for rutile-like pigments.;Titania is ... large ... crystals (translucent water-white or with yellowish cast) these crystals have refractive index ... higher than diamonds ... but lack hardness of diamonds.;Possesses perhaps the greatest hiding power of all inorg white pigments;Brown tetragonal crystals; MP: 1560 °C; density: 3.9 g/cu cm /Titanium(IV)oxide (Anatase)/;White, orthorhombic crystals; density: 4.17 g/cu cm /Titanium(IV)oxide (Brookite)/;White, tetrahedral crystals; MP: 1843 °C; BBP: approximately 3000 °C; density: 4.17 g/cu cm. Insoluble in water, dilute acid; soluble in concentrated acid /Titanium(IV)oxide (Rutile)/
Packaging
50 g/100 g/500 g
Refractive Index
n20/D 1.520
Rotatable Bond Count
0
Vapor Pressure
0 mm Hg at 68 °F Essentially (NTP, 1992);0 mmHg (approx);0 mmHg (approx)
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