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  • Tetramethylammonium hydroxide

  • Tetramethylammonium hydroxide

    Catalog Number
    ACM75592-1
    Product Name
    Tetramethylammonium hydroxide
    Structure
    CAS
    75-59-2
    Category
    Polymers
    Description
    Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia-like odor. It is soluble in water. It is corrosive to metals and tissue.;Liquid
    IUPAC Name
    tetramethylazanium;hydroxide
    Molecular Weight
    91.15g/mol
    Molecular Formula
    C4H13NO
    Canonical SMILES
    C[N+](C)(C)C.[OH-]
    InChI
    InChI=1S/C4H12N.H₂O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1
    InChI Key
    WGTYBPLFGIVFAS-UHFFFAOYSA-M
    Melting Point
    63 °C
    Density
    Specific gravity of solution approximately 1.00 at 24 °C/4 °C
    Solubility
    In water, 1.0X10+6 mg/L at 25 °C /miscible/ (est)
    Color/Form
    The free base is known only in solution or as a solid pentahydrate, forming colorless, deliquescent needles;Liquid
    Complexity
    19.1
    Corrosivity
    Corrosive
    Covalently-Bonded Unit Count
    2
    EC Number
    200-882-9
    Exact Mass
    91.099714g/mol
    Formal Charge
    0
    Heavy Atom Count
    6
    Log P
    log Kow = -2.47 (est)
    MeSH Entry Terms
    tetraamethylammonium acetate;tetramethylammonium;tetramethylammonium bromide;tetramethylammonium chloride;tetramethylammonium fluoride;tetramethylammonium hydrogen dichloride;tetramethylammonium hydroxide;tetramethylammonium hydroxide pentahydrate;tetramethylammonium iodide;tetramethylammonium nitrate;tetramethylammonium perchlorate;tetramethylammonium sulfate (2:1);tetramethylammonium tribromide;tetramethylammonium triiodide;trimethylaminomethane
    Monoisotopic Mass
    91.099714g/mol
    Odor
    Strong ammonia-like
    Other Experimental
    Decomposes to trimethylamine and methanol upon distillation;Readily absorbs CO2 from the air;When heated to decomposition it emits toxic fumes of NOx and NH₃.;Concn: 25 wt% in water. VP: 17.5 mm Hg at 20 °C; Index of refraction: 1/3806 at 20 °C/D; density: 1.106 g/mL at 25 °C /Tetramethylammonium hydroxide solution/;Henry's Law constant = 4.35X10-16 atm-cu m/mol at 25 °C (est);Hydroxyl radical reaction rate constant = 5.06X10-12 cu cm/molec-sec at 25 °C (est)
    Rotatable Bond Count
    0
    Stability
    Stable under recommended storage conditions. /Tetramethylammonium hydroxide pentahydrate/
    UNII
    5GKP7317Q2
    UN Number
    1835;1835;1835
    Vapor Pressure
    1.16X10-6 mm Hg at 25 °C (est)
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