CAS 14284-93-6 Ruthenium(III) acetylacetonate

NAVIGATION

Ruthenium(III) acetylacetonate

PRICE INQUIRY

Catalog Number

ACM14284936-9

CAS Number

14284-93-6

Product Name

Ruthenium(III) acetylacetonate

Structure

Category

Solution Deposition Precursors

Synonyms

Acetylacetone ruthenium(III) salt

IUPAC Name

(Z)-4-Hydroxypent-3-en-2-one;ruthenium

Molecular Weight

401.4

Molecular Formula

C15H24O6Ru

Canonical SMILES

CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Ru]

InChI

InChI=1S/3C5H8O2.Ru/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/b3*4-3-;

InChI Key

IYWJIYWFPADQAN-LNTINUHCSA-N

Melting Point

260 °C

Purity

95%+

Solubility

Soluble in most organic solvents

Appearance

White crystalline

Application

Ruthenium(III) acetylacetonate serves as a valuable precursor for synthesizing various ruthenium compounds. This dark-red crystalline complex is widely utilized as a recyclable catalyst in organic transformations, including the acetylation of phenols, alcohols, and amines, conducted under neat conditions. It also functions as a homogeneous catalyst in processes such as the hydrolysis of sodium borohydride and the regiospecific tritiation of aromatic carboxylic acids. Additionally, Ruthenium(III) acetylacetonate is employed as a catalyst for the enantioselective hydrogenation of acids, including aryl acrylic acid and aryl propenic acid, demonstrating its versatility and effectiveness in catalytic applications.

Storage

Store below +30 °C

Complexity

380

Covalently-Bonded Unit Count

EC Number

238-193-0

Exact Mass

402.061629

Formal Charge

Heavy Atom Count

Monoisotopic Mass