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Rhenium(III) chloride

Catalog Number
ACM13569636-3
CAS Number
13569-63-6
Product Name
Rhenium(III) chloride
Structure
Category
Electrolytes
Synonyms
Rhenium trichloride
IUPAC Name
trichlororhenium;
Molecular Weight
292.57
Molecular Formula
ReCl₃
Canonical SMILES
Cl[Re](Cl)Cl;
InChI
InChI=1S/3ClH.Re/h3*1H;/q;;;+3/p-3;
InChI Key
LOIHSHVELSAXQN-UHFFFAOYSA-K;
Boiling Point
>550° C
Application
Rhenium(III) chloride serves as a foundational reagent in the synthesis of rhenium complexes, demonstrating its utility as a catalyst in chemical reactions. This dark-red solid releases a green vapor upon heating, facilitating the deposition of metallic rhenium. It is soluble in water and glacial acetic acid, highlighting its versatile nature in various solvents, though it does not act as an electrolyte in solution. Rhenium(III) chloride's ability to react with peralkylated benzene-metal complexes, which function as electron reservoirs, underscores its significance in advanced synthetic chemistry.
Storage
room temperature
Complexity
8
Covalently-Bonded Unit Count
1
EC Number
236-987-1
Exact Mass
291.862g/mol
Heavy Atom Count
4
Monoisotopic Mass
291.862g/mol
Topological Polar Surface Area
0A^2
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