Catalog Number
ACM30604810
Category
3D Printing Materials; Bioelectronic Materials
Description
Polypyrrole (PPy) is a conductive and highly stable polymer. It may be prepared by a standard electrochemical technique.PPy may also be prepared by reacting ß-napthalene sulfonic acid (NSA) and ammonium peroxo-disulphate in aqueous medium. The charges on the surfaces can be easily modified by doping the polymer during its synthesis. Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid has been reported.Electrosensitivity and lower oxidation potential of PPy make it potentially useful for drug delivery, chemical sensors, batteries, ion selective electrodes, biosensor and biochemistry research.
Molecular Weight
67.09g/mol
Canonical SMILES
C1=CNC=C1
InChI
1S/C4H5N/c1-2-4-5-3-1/h1-5H
InChI Key
KAESVJOAVNADME-UHFFFAOYSA-N
Boiling Point
129.7 °C;129.7 °C
Flash Point
102 °F (39 °C) (CLOSED CUP)
Density
d204 0.97;0.9698 @ 20 °C;0.955-0.975
Solubility
0.67 M;45 mg/mL at 25 °C;Soluble in alcohol, ether and dilute acids. Also soluble in most organic chemicals.;Water solubility: 4.5X10+4 mg/l @ 25 °C;45 mg/mL at 25 °C;Soluble in most fixed oils; Slightly soluble in water;Soluble (in ethanol)
Application
PPy may be used to prepare cobalt based electrocatalyst for anion exchange membrane fuel cells.
Color/Form
Colorless liquid when fresh;Yellowish or brown oil
Covalently-Bonded Unit Count
1
EC Number
240-327-8;203-724-7
Heat of Vaporization
10.79 kcla/mol @ 25 °C
Log P
0.75 (LogP);0.75;log Kow = 0.75;0.75
MeSH Entry Terms
polypyrrole
Monoisotopic Mass
67.042199g/mol
Odor
Agreeable empyreumatic odor resembling that of chloroform
Other Experimental
Polymerizes under influence of acids and glycols; soln in dil hydrogen chloride yield pyrrole red, an amorphous, orange-colored substance;Decomposes in acid; Conversion factors: 1 mg/l= 3.64 ppm; 1 ppm= 2.74 mg/cu m;Hydroxyl radical rate constant = 1.1X10-10 cu m/molc-sec @ 25 °C;Henry's Law constant = 1.80X10-5 atm-cu m/mol @ 25 °C;Hygroscopic
Packaging
10 g in glass bottle
Refractive Index
n20D 1.5085;Index of refraction: 1.5085 @ 20 °C/D;1.507-1.510
Stability
DARKENS ON STANDING WITH EXPOSURE TO AIR.
Vapor Density
2.31 (Air= 1)
Vapor Pressure
8.36 mmHg;8.35 mm Hg @ 25 dec C
Viscosity
4.1123X10-3 Pa.s @ 249.74K