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Polypyrrole

Catalog Number
ACM30604810
CAS Number
30604-81-0
Product Name
Polypyrrole
Structure
Category
3D Printing Materials; Bioelectronic Materials
Synonyms
PPy
Description
Polypyrrole (PPy) is a conductive and highly stable polymer. It may be prepared by a standard electrochemical technique.PPy may also be prepared by reacting ß-napthalene sulfonic acid (NSA) and ammonium peroxo-disulphate in aqueous medium. The charges on the surfaces can be easily modified by doping the polymer during its synthesis. Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid has been reported.Electrosensitivity and lower oxidation potential of PPy make it potentially useful for drug delivery, chemical sensors, batteries, ion selective electrodes, biosensor and biochemistry research.
IUPAC Name
1H-pyrrole
Molecular Weight
67.09g/mol
Molecular Formula
C4H5N
Canonical SMILES
C1=CNC=C1
InChI
1S/C4H5N/c1-2-4-5-3-1/h1-5H
InChI Key
KAESVJOAVNADME-UHFFFAOYSA-N
Boiling Point
129.7 °C;129.7 °C
Melting Point
>300 °C
Flash Point
102 °F (39 °C) (CLOSED CUP)
Density
d204 0.97;0.9698 @ 20 °C;0.955-0.975
Solubility
0.67 M;45 mg/mL at 25 °C;Soluble in alcohol, ether and dilute acids. Also soluble in most organic chemicals.;Water solubility: 4.5X10+4 mg/l @ 25 °C;45 mg/mL at 25 °C;Soluble in most fixed oils; Slightly soluble in water;Soluble (in ethanol)
Appearance
Black power
Application
PPy may be used to prepare cobalt based electrocatalyst for anion exchange membrane fuel cells.
Storage
room temp
Color/Form
Colorless liquid when fresh;Yellowish or brown oil
Complexity
22.8
Covalently-Bonded Unit Count
1
EC Number
240-327-8;203-724-7
Exact Mass
67.042199g/mol
Form
solid
Formal Charge
0
Heat of Vaporization
10.79 kcla/mol @ 25 °C
Heavy Atom Count
5
Log P
0.75 (LogP);0.75;log Kow = 0.75;0.75
MDL Number
MFCD00284347
MeSH Entry Terms
polypyrrole
Monoisotopic Mass
67.042199g/mol
NSC Number
72470;62777
Odor
Agreeable empyreumatic odor resembling that of chloroform
Other Experimental
Polymerizes under influence of acids and glycols; soln in dil hydrogen chloride yield pyrrole red, an amorphous, orange-colored substance;Decomposes in acid; Conversion factors: 1 mg/l= 3.64 ppm; 1 ppm= 2.74 mg/cu m;Hydroxyl radical rate constant = 1.1X10-10 cu m/molc-sec @ 25 °C;Henry's Law constant = 1.80X10-5 atm-cu m/mol @ 25 °C;Hygroscopic
Packaging
10 g in glass bottle
Refractive Index
n20D 1.5085;Index of refraction: 1.5085 @ 20 °C/D;1.507-1.510
Rotatable Bond Count
0
Stability
DARKENS ON STANDING WITH EXPOSURE TO AIR.
Type
Polypyrrole
UNII
86S1ZD6L2C
Vapor Density
2.31 (Air= 1)
Vapor Pressure
8.36 mmHg;8.35 mm Hg @ 25 dec C
Viscosity
4.1123X10-3 Pa.s @ 249.74K
XLogP3
0.7
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