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  • N,N-Bis(Trimethylsilyl)Allylamine

  • N,N-Bis(Trimethylsilyl)Allylamine

    Catalog Number
    ACM7688519-2
    CAS Number
    7688-51-9
    Product Name
    N,N-Bis(Trimethylsilyl)Allylamine
    Structure
    Category
    Salt
    Synonyms
    578932_ALDRICH, EINECS 231-699-2, MolPort-003-937-319, N,N-Bis(trimethylsilyl)allylamine, CID82125, N-Allyl-N,N-bis(trimethylsilyl)amine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine, Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-, 7688-51-9
    IUPAC Name
    N,N-bis(trimethylsilyl)prop-2-en-1-amine
    Molecular Weight
    201.46 g/mol
    Molecular Formula
    C9H23NSi2
    Canonical SMILES
    C[Si](C)(C)N(CC=C)[Si](C)(C)C
    InChI Key
    CVNCFZIIZGNVFD-UHFFFAOYSA-N
    Boiling Point
    72ºC15 mm Hg(lit.)
    Flash Point
    109 °F
    Purity
    95%+
    Density
    0.816 g/mL at 25ºC(lit.)
    Appearance
    Transparent liquid
    Application
    N,N-Bis(Trimethylsilyl)Allylamine serves as a versatile nucleophilic reagent in organic synthesis. It enables the construction of complex bicyclic scaffolds through reactions with aryl aldehydes via imine formation, followed by efficient multicomponent reactions. Additionally, it can react with bisthiocarbamoyl chloride to form dithiasuccinoyl heterocycles, and with aryl selenium salts in the presence of a ruthenium catalyst to produce allyl selenide. The latter is particularly valuable as a key intermediate in various organic synthesis processes. Beyond these applications, N,N-Bis(Trimethylsilyl)Allylamine is also employed in hydrosilylation and hydroboration reactions and may serve as an additive in electrolytes.
    EC Number
    231-699-2
    Exact Mass
    201.13700
    Hazard Statements
    Xi
    Packaging
    10 g; 100 g;
    Safety Description
    16-26-36/37
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