1-Methoxy-1-trimethylsilyloxypropene

Name: 1-Methoxy-1-trimethylsilyloxypropene
SKU: ACM34880701-2
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Catalog NumberACM34880701-2

CAS Number34880-70-1

CategoryPolymerization Initiators; Polymerization Reagents

Synonyms

1-Methoxy-1-trimethylsilyloxypropene, 34880-70-1, [(1-Methoxy-1-propenyl)oxy]trimethylsilane, AG-F-19747, ACMC-1CTU0, CTK2H2224, CTK2H2225, CTK3J6429, ANW-28005, KB-12692, Silane, [[(1E)-1-methoxy-1-propenyl]oxy]trimethyl-, Silane, [[(1Z)-1-methoxy-1-propenyl]oxy]trimethyl-, 1-Methoxy-1-(trimethylsilyloxy)prop-1-ene;Methylketene methyl trimethylsilyl acetal; O-Methyl-O-trimethylsilylmethylketeneacetal, 72658-03-8, 72658-09-4

IUPAC Name

1-methoxyprop-1-enoxy(trimethyl)silane

Molecular Weight

160.29

Molecular Formula

C₇H₁₆O₂Si

Canonical SMILES

CC=C(OC)O[Si](C)(C)C

InChI Key

RTHAKVSHSCPUGI-UHFFFAOYSA-N

Boiling Point

52ºC / 27mmHg

Flash Point

23.505ºC

Purity

>95.0%(GC)

Density

0.87

Application

1-Methoxy-1-trimethylsilyloxypropene serves as a versatile reagent, facilitating a range of chemical transformations. Its primary purpose is to act as a reactive nucleophile in Mukaiyama-type aldol reactions, engaging efficiently with aldehydes, imines, acetals, dialkoxycarbenium ions, and orthoesters. Beyond aldol reactions, it is utilized in Michael-type additions to α,β-unsaturated carbonyl compounds, offers reactivity in substitution reactions with allylic alcohols and esters, and plays a role in acylations, aminations, hydroxylations, and pericyclic reactions. Additionally, it functions as a silylating agent, providing utility in diverse synthetic applications.

Exact Mass

160.09200

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