Catalog Number
ACM10099588
Product Name
Lanthanum(III) chloride
Synonyms
Lanthanum chloride anhydrous
IUPAC Name
Trichlorolanthanum
Canonical SMILES
Cl[La](Cl)Cl
InChI
InChI=1S/3ClH.La/h3*1H;/q;+3/p-3
InChI Key
ICAKDTKJOYSXGC-UHFFFAOYSA-K
Density
3.84 g/mL at 25 °C (lit.)
Solubility
Soluble in water
Appearance
White to almost white beads
Application
When heated in the presence of water vapor, lanthanum oxochloride is formed:
LaCl3 + H₂O→LaOCl + 2HCl
Heating with glass at elevated temperatures also forms oxochloride:
LaCl3 + SiO2→2LaOCl + SiCl4
Lanthanum chloride reacts with hydrogen sulfide when heated at 1100°C, forming lanthanum sulfide:
2LaCl3 + 3H2S→La2S3 + 3H2S
Reactions with ammonia and phosphine at elevated temperatures yield lanthanum nitride and phosphide, respectively:
LaCl3 + PH3→LaP + 3HCl
Lanthanum chloride is reduced to lanthanum metal when heated with an alkali or alkaline earth metal at temperatures above 1000°C:
LaCl3 + 3Li→La + 3LiCl
Storage
Inert atmosphere,Room Temperature
Monoisotopic Mass
243.812921
Topological Polar Surface Area
0 Ų