NAVIGATION


Lanthanum(III) chloride

Catalog Number
ACM10099588
CAS Number
10099-58-8
Product Name
Lanthanum(III) chloride
Structure
Category
Electrolytes
Synonyms
Lanthanum chloride anhydrous
IUPAC Name
Trichlorolanthanum
Molecular Weight
245.26
Molecular Formula
LaCl3
Canonical SMILES
Cl[La](Cl)Cl
InChI
InChI=1S/3ClH.La/h3*1H;/q;+3/p-3
InChI Key
ICAKDTKJOYSXGC-UHFFFAOYSA-K
Boiling Point
1812 °C
Melting Point
860 °C
Flash Point
1000 °C
Purity
99%+
Density
3.84 g/mL at 25 °C (lit.)
Solubility
Soluble in water
Appearance
White to almost white beads
Application
When heated in the presence of water vapor, lanthanum oxochloride is formed:

LaCl3 + H₂O→LaOCl + 2HCl

Heating with glass at elevated temperatures also forms oxochloride:

LaCl3 + SiO2→2LaOCl + SiCl4

Lanthanum chloride reacts with hydrogen sulfide when heated at 1100°C, forming lanthanum sulfide:

2LaCl3 + 3H2S→La2S3 + 3H2S

Reactions with ammonia and phosphine at elevated temperatures yield lanthanum nitride and phosphide, respectively:

LaCl3 + PH3→LaP + 3HCl

Lanthanum chloride is reduced to lanthanum metal when heated with an alkali or alkaline earth metal at temperatures above 1000°C:

LaCl3 + 3Li→La + 3LiCl
Storage
Inert atmosphere,Room Temperature
Complexity
8
Exact Mass
243.812921
Heavy Atom Count
4
Monoisotopic Mass
243.812921
Topological Polar Surface Area
0 Ų
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