CAS 14038-43-8 Iron(III) Hexacyanoferrate(II)

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Iron(III) Hexacyanoferrate(II)

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Catalog Number

ACM14038438

Product Name

Iron(III) Hexacyanoferrate(II)

Structure

CAS

14038-43-8

Category

Magnetic Metal Complexes

IUPAC Name

iron(2+);iron(3+);octadecacyanide

Molecular Weight

859.2g/mol

Molecular Formula

Fe4[Fe(CN)6]3;C18Fe7N18

Canonical SMILES

[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3]

InChI

InChI=1S/18CN.7Fe/c18*1-2;;;;;;;/q18*-1;3*+2;4*+3

InChI Key

DCYOBGZUOMKFPA-UHFFFAOYSA-N

Density

1.80 g/cu cm

Solubility

Mostly insoluble in hot or cold water. 6 mg/mL at 25 deg C;Insoluble in dilute acid, organic solvents;Slightly soluble in most organic solvents. Soluble in oxalic acid; precipitates on exposure to light;Solubility in 2-methoxyethanol = 10 g/L. Solubility in ethanol = 20 g/L;In water, 6 mg/mL at 25 °C

Color/Form

Dark blue powder;Purple powder;Relatively strongly colored

Complexity

127

Covalently-Bonded Unit Count

EC Number

237-875-5

Exact Mass

859.59988g/mol

Formal Charge

Heavy Atom Count

MeSH Entry Terms

Berlin blue;ferric ferrocyanide;ferrihexacyanoferrate;ferrocin;ferrotsin;Prussian blue

Monoisotopic Mass

859.59988g/mol

Other Experimental

Apart from poor fastness toward alkalies, its general fastness is good.;Primary particle size is less than 20 nm with a specific surface area of 100 square meters/gram.;Iron blue pigments are thermally stable for short periods at temperatures up to 180 °C...The powdered material presents an explosion hazard, the ignition point is 600-625 °C...The pigments are combustible in powder form, ignition in air being possible above 140 °C.;MW: 859.3 Daltons. Powder ranges from uniformly fine, dark granules to course light and dark-colored granules. The crystal structure of Prussian blue is a cubic lattice with the Fe(II) and Fe(III) atoms occupying the corners of the cube and the cyanide groups positioned on the sides./Prussian blue insoluble capsules/;Prussian blue insoluble may not bind to all radioactive elements and some radioactive elements may not undergo enterohepatic circulation, which is needed for Prussian blue insoluble binding and elimination.

Rotatable Bond Count

MSDS

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COA

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Spec Sheet

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