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Ethylmagnesiumbromide

Catalog Number
ACM925906-1
CAS Number
925-90-6
Product Name
Ethylmagnesiumbromide
Structure
Category
Salt
IUPAC Name
magnesium;ethane;bromide
Molecular Weight
133.27g/mol
Molecular Formula
C2H5BrMg
Canonical SMILES
C[CH2-].[Mg+2].[Br-]
InChI
InChI=1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q-1;;+2/p-1
InChI Key
FRIJBUGBVQZNTB-UHFFFAOYSA-M
Application
Ethylmagnesium bromide serves as a versatile reagent essential for synthesizing zirconium complexes with two phenoxy-imine chelate ligands, which are used in olefin polymerization. Typically sold as a dark brown solution, it can be dissolved in various ethers, such as diethyl ether, butyl ether, isopropyl ether, THF, and anisole. As a Grignard reagent, ethylmagnesium bromide can react with water to yield ethane, demonstrating its role in reactions like the conversion of ethyl acetate, in the presence of styrene and titanium(IV) isopropoxide, to yield (Z)-1-methyl-2-phenylcyclopropanol, offering a 42% yield.
Complexity
6
Covalently-Bonded Unit Count
3
EC Number
213-127-3
Exact Mass
131.9425g/mol
Formal Charge
0
Hazard Statements
H315-H319-H335
Heavy Atom Count
4
MeSH Entry Terms
ethyl magnesium bromide
Monoisotopic Mass
131.9425g/mol
Rotatable Bond Count
0
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