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Butyl Methacrylate (stabilized with HQ)

Catalog NumberACM97881

CAS Number97-88-1

CategoryMonomers

Butyl Methacrylate (stabilized with HQ)
Description
N-butyl methacrylate appears as a clear colorless liquid. Flash point 130°F. Less dense (7.5 lb / gal) than water and insoluble in water. Hence floats on water. Vapors heavier than air. Used to make resins adhesives, and oil additives.;Liquid;COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.
IUPAC Name
butyl 2-methylprop-2-enoate
Molecular Weight
142.2g/mol
Molecular Formula
C8H14O2;CH2C(CH3)COO(CH2)3CH3;C8H14O2
Canonical SMILES
CCCCOC(=O)C(=C)C
InChI
InChI=1S/C8H14O2/c1-4-5-6-10-8(9)7(2)3/h2,4-6H2,1,3H3
InChI Key
SOGAXMICEFXMKE-UHFFFAOYSA-N
Boiling Point
326.3 to 338.9 °F at 760 mm Hg (NTP, 1992);160.0 °C;160 °C;163 °C
Melting Point
less than -58 °F (NTP, 1992);-75.0 °C;freezing point: less than -75 °C;-50 °C
Flash Point
126 °F (NTP, 1992);126 °F (52 °C) (open cup);50 °C c.c.
Density
0.8975 at 68 °F (USCG, 1999);0.8936 g/cu cm at 20 °C;Relative density (water = 1): 0.9
Solubility
Insoluble (NTP, 1992);0.01 M;Very soluble in ethyl ether, ethanol;In water, 800 mg/L at 25 °C;Solubility in water, g/100ml at 25 °C: 0.08 (very poor)
Application
Butyl Methacrylate (stabilized with HQ) serves as a highly versatile monomer, frequently utilized in the formation of methacrylic resins and a range of industrial applications. This flammable, colorless liquid with a mild odor plays a pivotal role in the production of solvent coatings, adhesives, and oil additives, as well as in crafting emulsions for textiles, leather, and paper finishing. In dentistry, it is used as a cross-linking methacrylic monomer for developing dental composite materials and has applications in artificial nails. Additionally, Butyl Methacrylate acts as a plasticizing agent, contributing to excellent weather resistance, high gloss, color retention, and durability in polymers, with an intermediate glass transition temperature of 20 °C. Moreover, it finds utility in the production of organic glass, synthetic resins, rubber, varnish, and acts as a polymer plasticizer for enhancing the hardness of resins.
Color/Form
Colorless liquid
Complexity
127
Covalently-Bonded Unit Count
1
EC Number
202-615-1;618-468-5
Exact Mass
142.09938g/mol
Formal Charge
0
Heavy Atom Count
10
ICSC Number
1018
Log P
2.88 (LogP);log Kow = 2.88;2.26-3.01
MeSH Entry Terms
butyl methacrylate monomer
Monoisotopic Mass
142.09938g/mol
NSC Number
20956
Odor
Faint characteristic odor of esters
Other Experimental
Readily polymerized;Liquid water interfacial tension: 35 dynes/cm = 0.035 N/m at 20 °C; Heat of polymerization: -180 BTU/lb = -100 cal/g = -4.2X10+5 J/kg; Reid vapor pressure: low;Liquid heat capacity: 0.460 BTU/lb-F at 70 °F; Liquid thermal conductivity: 1.048 BTU-in/hr-sq ft-F at 70 °F; Saturated vapor density: 0.00203 lb/cu ft at 70 °F;It weighs about 7.5 lb/gal.;Henry's Law constant = 4.96X10-4 atm-cu m/mol at 25 °C (est);Hydroxyl radical reaction rate constant = 2.3X10-11 cu cm/molec-sec at 25 °C (est)
Refractive Index
Index of refraction: 1.4240 at 20 °C/D
Rotatable Bond Count
5
RTECS Number
OZ3675000
UNII
R5QX287XXU
UN Number
2227;2227;2227;2227
Vapor Density
4.9 (NTP, 1992) (Relative to Air);4.8 (Air = 1);Relative vapor density (air = 1): 4.9
Vapor Pressure
1.8 mm Hg at 68 °F (NTP, 1992);2.12 mmHg;2.12 mm Hg at 25 °C;Vapor pressure, kPa at 20 °C: 0.3
Viscosity
3.116 cP at 70 °F;1.02 mm2/s at 24 °C
XLogP3
2.9
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